| Hydrothermal synthesis,structure study and luminescent properties of YbPO4:Tb3+ nanoparticles |
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| 作者姓名： | 张文妍 倪亚茹 黄文娟 陆春华 许仲梓 |
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| 作者单位： | State Key Laboratory of Materials-Orient Chemical Engineering,College of Materials Science and Engineering,Nanjing University of Technology |
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| 基金项目： | Project supported by National Natural Science Foundation of China (20901040/B0111);the Natural Science Foundation of the Jiangsu Higher Education Institutions,China (08KJB480001);the Natural Science Foundation of Jiangsu Province (BK2004121);the major program for the Natural Science Fundamental Research of the Jiangsu Higher Education Institutions of China and the Innovation Foundation for Graduate Stu-dents of Jiangsu Province (CX10B_159Z) |
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| 摘 要： | YbPO4:Tb3+ were synthesized by mild hydrothermal method.The luminescent properties,morphologies and structure of the obtained powders were characterized by photoluminescence(PL) spectra,FESEM,X-ray diffractometer(XRD) and FTIR.The results showed that the prepared YbPO4:Tb3+ nanoparticles were pure tetragonal phase and the average grain size varied with increasing of Tb3+ concentration.Hydrothermal temperature was revealed to be the key factor to enhance the emission intensity of YbPO4:Tb3+ phosphors.The spherical nanoparticles could be effectively excited by near UV(369 nm) light and exhibited green performance at 543 nm(5D4→7F5),489 nm(5D4→7F6) and 586 nm(5D4→7F4).The CIE chromaticity was calculated to be x=0.298,y=0.560.The YbPO4:Tb3+ nanoparticles exhibited potential to act as UV absorber for solar cells to enhance the conversion efficiency.
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| 关 键 词： | luminescence hydrothermal YbPO4:Tb3+ nanoparticle rare earths |
Hydrothermal synthesis,structure study and luminescent properties of YbPO<sub>4</sub>:Tb<sup>3+</sup> nanoparticles |
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| ZHANG Wenyan,NI Yaru,HUANG Wenjuan,LU Chunhua,XU Zhongzi.Hydrothermal synthesis,structure study and luminescent properties of YbPO4:Tb3+ nanoparticles[J].Journal of Rare Earths,2010(Z1):299-302. |
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| Authors: | ZHANG Wenyan NI Yaru HUANG Wenjuan LU Chunhua XU Zhongzi |
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| Affiliation: | (State Key Laboratory of Materials-Orient Chemical Engineering,College of Materials Science and Engineering,Nanjing University of Technology,Nanjing 210009,China) |
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| Abstract: | YbPO4:Tb3+ were synthesized by mild hydrothermal method.The luminescent properties,morphologies and structure of the obtained powders were characterized by photoluminescence(PL) spectra,FESEM,X-ray diffractometer(XRD) and FTIR.The results showed that the prepared YbPO4:Tb3+ nanoparticles were pure tetragonal phase and the average grain size varied with increasing of Tb3+ concentration.Hydrothermal temperature was revealed to be the key factor to enhance the emission intensity of YbPO4:Tb3+ phosphors.The spherical nanoparticles could be effectively excited by near UV(369 nm) light and exhibited green performance at 543 nm(5D4→7F5),489 nm(5D4→7F6) and 586 nm(5D4→7F4).The CIE chromaticity was calculated to be x=0.298,y=0.560.The YbPO4:Tb3+ nanoparticles exhibited potential to act as UV absorber for solar cells to enhance the conversion efficiency. |
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| Keywords: | luminescence hydrothermal YbPO4:Tb3+ nanoparticle rare earths |
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