Simulation of f-d transition using the extended crystal-field model:parameter dependent study for Er3+ in various hosts |
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Authors: | DUAN Changkui ZHANG You MA Chonggeng XIE Guoya HU Liusen |
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Affiliation: | 1.Institute of Modern Physics,Chongqing University of Post and Telecommunicat ions,Chongqing 400065,China;2.Department of Biology and Chemistry,City Univ ersity of Hong Kong,Tat Chee Avenue,Kowloon,Hong Kong S.A.R.,China;3.Colle ge of Mathematics and Physics,Chongqing University of Post and Telecommunicatio ns,Chongqing 400065,China;4.Department of Physics,University of Science and Technology of China,Hefei 230026,China) |
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Abstract: | The 4f-5d transitions of Er3+ ions doped in crystals were widely studi ed due to their potential applications in quantum cutting phosphors and VUV lase rs,etc.The theory to do the calculations of 4f-5d transitions and various rela ted aspects,such as the ways to determining various parameters,were summarized .The impacts of various interactions on the spectra were also demonstrated clea rly with Er3+ ions in crystals CaF2 and LiYF4.Predicted results were compared w ith measured spectra. |
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Keywords: | f-d transitions Er3+ crystal-field interactions LiYF4 CaF2 Cs2NaY F6 rare earths |
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