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Adsorption of carbon dioxide by coconut activated carbon modified with Cu/Ce
Authors:LI Fenrong  YI Honghong  TANG Xiaolong  NING Ping  YU Qiongfen  KANG Dongjuan
Affiliation:College of Environmental Science and Engineering,Kunming University of Science & Technology
Abstract:A series of the coconut activated carbons(CAC) based absorbents modified with Cu and Ce(Cu/CAC,Cu/Ce/CAC) were prepared by impregnation technology for carbon dioxide capture.The adsocrption equilibriums of CO2 on Cu/CAC and Cu/Ce/CAC were measured.The results showed that the adsorption capacity of CO2 onto the activated carbon modified with Cu/Ce increased with the decreasing temperature in the same pressure.The adsorption capacity of CO2 on Cu/CAC was higher than that of the blank CAC,and compared with the Cu/CAC,the adsorption capacity of CO2 of Cu/Ce/CAC with the mass ratio of Cu/Ce=30 was improved at 298 and 303 K.In addition,the adsorption equilibrium data for CO2 at various temperatures was fitted to Langmuir,Freundlich and D-R isotherm models.It was found that the D-R equation was the best model for fitting the adsorption data on Cu/Ce/CAC at different temperatures.
Keywords:adsorption  CO2 capture  Cu  Ce  rare earths
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