Stress-strain behavior of the craze

The constitution and properties of crazes in glassy polymers and their relation to crack propagation are reviewed. New evidence is discussed which shows the craze to be much softer than the parent polymer but capable of sustaining large stresses and strains up to the point of failure. Craze failure is much more dependent on polymer molecular weight than is craze formation, and this difference is reflected in changes in both fracture surface morphology and crack toughness with molecular weight. Finally craze mechanical properties are thought to be integrally related to the mechanical behavior of high impact plastics.