| 碳四芳构化液相产物中少量重组分的脱烷基反应 |
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| 引用本文： | 王小强,刘飞,程亮亮,马应海,马艳捷,黄剑锋. 碳四芳构化液相产物中少量重组分的脱烷基反应[J]. 石化技术与应用, 2013, 31(4): 288-291 |
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| 作者姓名： | 王小强 刘飞 程亮亮 马应海 马艳捷 黄剑锋 |
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| 作者单位： | 中国石油兰州化工研究中心,甘肃兰州,730060 |
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| 摘 要： | 以混合碳四芳构化反应液相产物为原料,采用MO/HMCM-56重芳烃脱烷基制苯、甲苯、二甲苯(BTX)催化剂,研究了芳构化液相产物中少量重组分的脱烷基反应性能。结果表明,在反应温度为460℃,反应压力为3.0 MPa,氢油体积比为1 600,质量空速为3.62 h-1的工艺条件下,在液相产物汽油馏分(馏程低于205℃)中,BTX质量分数至少可提高21.65个百分点;原料中柴油馏分(馏程不低于205℃)质量分数为9.5%,液相产物中柴油馏分的质量分数最低可降至2.0%。
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| 关 键 词： | 芳构化 重芳烃 脱烷基 |
Dealkylation reaction of a small amount of heavy components in aromatized C4 liquid product |
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| WANG Xiao-qiang , LIU Fei , CHENG Liang-liang , MA Ying-hai , MA Yan-jie , HUANG Jian-feng. Dealkylation reaction of a small amount of heavy components in aromatized C4 liquid product[J]. Petrochemical Technology & Application, 2013, 31(4): 288-291 |
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| Authors: | WANG Xiao-qiang LIU Fei CHENG Liang-liang MA Ying-hai MA Yan-jie HUANG Jian-feng |
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| Affiliation: | WANG Xiao - qiang, LIU Fei, CHENG Liang - liang, MA Ying - hal, MA Yan- jie, HUANG Jian - feng ( LanZhou Petrochemical Research Center, PetroChina, LanZhou 730060, China) |
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| Abstract: | The dealkylation reaction of a small a- mount of heavy components in aromatized C4 liquid product was investigated with the catalyst MO/HM- CM- 56 of heavy aromatics dealkylation for ben- zene,toluene and xylene （BTX）. The results showed that under the condition of temperature 460 ℃, reac- tion pressure 3.0 MPa, volume ratio of hydrogen to material oil 1600 ： 1, weight space velocity 3.62 h - 1, BTX mass fraction in the gasoline fraction（ boiling range was less than 205 ℃ ） of liquid prod- uct increased by over 21.65 percent points ,the mass fraction of diesel fraction （ boiling range was no less than 205 ℃ ） in material oil was 9.5% , and the mass fraction of diesel in liquid product could be de- creased to the minimum of 2%. |
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| Keywords: | aromatization heavy aromatics dealkylation |
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