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Bulk Grain Resistivity of ZnO-Based Varistors
Authors:A. C. Caballero  D. Fernández Hevia  J. de Frutos  M. Peiteado  J. F. Fernández
Affiliation:(1) Dpto. de Electrocerámica, Instituto de Cerámica y Vidrio, CSIC, 28049 Cantoblanco, Madrid, Spain;(2) E.T.S.I. Telecomunicación, Univ. Politécnica de Madrid, Ciudad Universitaria s/n, 28040 Madrid, Spain
Abstract:We study the temperature dependence of grain resistivity in ZnO ceramic varistors (300–430 K), finding a positive temperature coefficient (PTC). We devise a high-frequency procedure that allow us to obtain the concentration and energy position of the shallow donor. The observed behavior is consistent with a shallow donor approaching complete ionization, and with an electron mobility mainly controlled by lattice (both optical and acoustical) scattering. The impact of this behavior on varistor performance under high-current pulse loads is discussed.
Keywords:varistors  electrical properties  bulk conductivity
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