The microstructure of sintered Si-Al-O-N ceramics

Fine-grained ceramics, based on the substituted -Si₃N₄ crystal structure, have been prepared with near theoretical densities by pressureless sintering of compacts containing a large Y₂O₃ additive concentration. The microstructure contains two phases, and an Y/Al rich silicate glassy matrix, in the as-sintered condition. The matrix may be crystallized on heat treatment to a Si-substituted yttrium-aluminium garnet phase. The phase compositions and transformation mechanisms have been analysed by X-ray microanalysis, electron diffraction and imaging of thin sections.A preliminary survey of mechanical properties of these sintered ceramics shows that they are comparable with commercial hot-pressed silicon nitrides, particularly at high temperatures. The possibility of development of a range of ceramic alloys, dependent on their chemical environment and temperature of application, is discussed.