Directional solidification and physical properties measurements of the zinc-aluminum eutectic alloy

Zn-5wt％ Al eutectic alloy was directionally solidified with different growth rates (5.32-250.0 tm/s) at a constant temperature gradient of 8.50 K/mm using a Bridgman-type growth apparatus.The values of eutectic spacing were measured from transverse sections of the samples.The dependences of the eutectic spacing and undercooling on growth rate are determined as λ=9.21 V-0.53 and △T=0.0245 V0.53,respectively.The results obtained in this work were compared with the Jackson-Hunt eutectic theory and the similar experimental results in the literature.Microhardness of directionally solidified samples was also measured by using a microhardness test device.The dependency of the microhardness on growth rate is found as Hv=115.64V0.13.Afterwards,the electrical resistivity (r) of the casting alloy changes from 40× 10-9 to 108× 10-9 Ω·m with the temperature rising in the range of 300-630 K.The enthalpy of fusion (△H) and specific heat (Cp) for the Zn-Al eutectic alloy are calculated to be 113.37 J/g and 0.309 J/(g.K),respectively by means of differential scanning calorimetry (DSC) from heating trace during the transformation from liquid to solid.