1D Coordination Polymer from Tetraaza Macrocyclic Nickel(II) Complex and 1,2,3,4-Cyclobutanetetracarboxylic Acid |
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Authors: | Ki-Young Choi In-Taek Lim |
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Affiliation: | 1. Department of Chemistry Education, Kongju National University, Kongju, 314-701, Korea
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Abstract: | The self assembly of Ni(L)]Cl2·2H2O (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo14,4,01.18,07.12]docosane) and 1,2,3,4-cyclobutanetetracarboxylic acid (H4cbtc) acid generates a 1D coordination and 2D hydrogen-bonded polymer Ni(L)(H2cbtc)2·3H2O] n (1). Complex 1 is characterized by X-ray crystallography, spectroscopy and magnetic susceptibility. Each nickel(II) ion has a distorted octahedral coordination environment with the four secondary amines of the macrocycle in which two carboxylate anions of the H2cbtc2? ligand have assembled around each nickel center. The compound crystallizes in the triclinic system P-1 with a = 9.715(3) Å, b = 12.891(5) Å, c = 13.903(6) Å, α = 72.64(2)°, β = 75.70(3)°, γ = 73.27(3)°, V = 1566.6(10) Å3, Z = 2. The electronic spectrum of 1 indicates a high-spin octahedral environment. The magnetic behavior of 1 reveals a weak intramolecular antiferromagnetic interaction with J = ?1.23(1) cm?1. |
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