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Investigations on electrodeposition of nickel from dimethylsulfoxide
Authors:S. Biallozor  A. Lisowska-Oleksiak  M. Lieder
Affiliation:Institute of Inorganic Chemistry and Technology of Technical University, 80-952 Gdańsk, Poland
Abstract:Process of cathodic deposition of nickel mainly from Ni(BF4)2 solution in DMSO has been investigated using various experimental techniques. It has been found that this process is complicated. The collected experimental data indicate that passivation of fresh cathodic layer of Ni by chemisorption of DMSO molecules takes place. By basing on the rde methods the values of αnm = 0.4 (± 0.05) and kfh = f(Ec) have been estimated.
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