Rate of electrochemical formation of nanoclusters |
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| Authors: | V A Isaev O V Grishenkova |
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| Affiliation: | 1.Institute of High-Temperature Electrochemistry, Ural Division,Russian Academy of Sciences,Yekaterinburg,Russia |
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| Abstract: | The electrochemical formation of nanoclusters is considered. The classical thermodynamic and atomistic theories of nucleation
are compared. A version is proposed for the atomistic approach of the theory that is suitable for the region of high supersaturations
(overvoltages). The concept of the critical cluster of a new phase is analyzed. A method for determining the number of atoms
in the critical cluster of a new phase during electrolytic crystallization is suggested. |
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