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Hyperbranched poly(cyanurateamine): A new corrosion inhibitor for mild steel in hydrochloric acid medium
Authors:D. Thirumoolan  Vikas A. Katkar  G. Gunasekaran  Tapan Kanai  K. Anver Basha
Affiliation:1. PG & Research Department of Chemistry, C. Abdul Hakeem College, Melvisharam 632509, District Vellore, Tamilnadu, India;2. Protective Technologies Division, Naval Materials Research Laboratory, Shil Badlapur Road, Addl. Ambernath (E) 421506, District Thane, India
Abstract:Hyperbranched poly(cyanurateamine) (POCYAM) was tested as a novel corrosion inhibitor for mild steel in 0.5–3 M HCl using chemical and electrochemical techniques at 25–70 °C. The results show that this compound has good corrosion inhibiting properties for mild steel in HCl at very low concentrations. Corrosion inhibition efficiency rises with POCYAM concentration. The adsorption of the POCYAM onto the mild steel surface obeys Langmuir adsorption isotherm model. The inhibition mechanism was further corroborated by the values of thermodynamic parameters obtained from the experimental data.
Keywords:Mild steel   Polarization   EIS   SEM
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