A fully bio-based waterborne polyurethane dispersion from vegetable oils: From synthesis of precursors by thiol-ene reaction to study of final material |
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| Authors: | Changqing Fu Zitong Zheng Zhe Yang Yiwang Chen Liang Shen |
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| Affiliation: | 1. Institute of Polymers, Nanchang University, Nanchang 330031, PR China;2. Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science & Technology Normal University, Nanchang 330013, PR China |
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| Abstract: | A new linear saturated terminal diisocyanate was synthesized from castor oil-derived undecylenic acid by thiol-ene coupling (TEC) and Curtius rearrangement. The structure of the diisocyanate was carefully examined using Fourier transform infrared spectroscopy, 1H nuclear magnetic resonance (NMR), and 13C NMR. This diisocyanate was used as a starting material for the preparation of a fully bio-based waterborne polyurethane dispersion (BPUD) by reacting with castor oil and castor oil-based carboxylic acid-type hydrophilic chain extender, which was prepared from castor oil by using 3-mercaptopropionic acid via TEC. The thermal/mechanical properties of the formed BPUD film were characterized via differential scanning calorimetry, thermogravimetric analysis, tensile test, hardness test, and water resistance test. The fatty acid-derived diisocyanate and the castor oil-based hydrophilic chain extender were used to produce BPUD with favorable properties. |
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| Keywords: | Waterborne polyurethane Bio-based Diisocyanates Chain extender Thiol-ene |
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