Synthesis and characterization of Schiff base derivative with pyrrole ring and electrochromic applications of its oligomer |
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| Authors: | ?smet Kaya Ercan BoraAysel Ayd?n |
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| Affiliation: | Çanakkale Onsekiz Mart University, Faculty of Sciences and Arts, Department of Chemistry, Polymer Synthesis and Analysis Laboratory, 17020 Çanakkale, Turkey |
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| Abstract: | In this study, Schiff base monomer, 2-(1H-pyrrol-2-yl-methylene)amino]phenol (2-PMAP) was obtained by condensation reaction of 2-aminophenol with pyrrole-2-carbaldehyde. This monomer was oxidized in an aqueous alkaline medium by NaOCl to obtain the corresponding oligomer (O-2-PMAP). The resulting compounds were characterized by 1H- and 13C-NMR, FT-IR, UV–vis, TG-DTA and size exclusion chromatography (SEC) techniques. Metal complexes compounds of O-2-PMAP were prepared with various metal salts, such as Cu (AcO)2·H2O, Zn (AcO)2·2H2O, Cd (AcO)2·2H2O, Pb (AcO)2·3H2O and Co (AcO)2·4H2O. In addition to this, electrochemical copolymerization of O-2-PMAP with thiophene (Th), 3,4-ethylenedioxythiophene (EDOT) and pyrrole (Py) were performed onto indium/tin oxide (ITO)-coated glass plate. The spectral changes of the co-polymeric films were recorded in the range of the different potentials. The film stabilities of its EDOT and Py copolymers were determined. Consequently, it was realized that the copolymer films kept their stability for a long time. |
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| Keywords: | Electropolymerization Electrochromism Imine oligomer Oxidative polycondensation Thermal degradation |
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