| 导电聚邻苯二胺的合成及在染料敏化太阳能电池中的应用 |
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| 引用本文： | 吴颉,张修华,王世敏.导电聚邻苯二胺的合成及在染料敏化太阳能电池中的应用[J].胶体与聚合物,2007,25(1):37-39. |
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| 作者姓名： | 吴颉 张修华 王世敏 |
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| 作者单位： | 湖北大学化材学院,武汉,430062 |
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| 摘 要： | 制备了聚邻苯二胺,并将其作固体传输材料应用在染料敏化太阳能电池中。用光电化学方法研究了染料酸性湖蓝、聚邻苯二胺(PoPD)、二氧化钛(TiO2)纳米晶电极以及用酸性湖蓝和PoPD复合敏化TiO2纳米晶膜电极的光电化学行为。用聚邻苯二胺作为固体电解质,染料酸性湖蓝,组装了电池,初步测定了TiO2/酸性湖蓝/PoPD电极作为光阳极的光电化学电池的工作特性曲线,测得Voc=0.43V,Isc=0.378mA。
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| 关 键 词： | 聚邻苯二胺 酸性湖蓝 固体电解质 |
| 修稿时间： | 2006年10月30 |
Synthesize of conducting PoPD and its application in DSSCs |
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| Jie Wu,Zhang Xiuhua,Shimin Wang.Synthesize of conducting PoPD and its application in DSSCs[J].Chinese Journal of Colloid and Polymer,2007,25(1):37-39. |
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| Authors: | Jie Wu Zhang Xiuhua Shimin Wang |
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| Affiliation: | Faculty of Chemistry and Material Science Hubei University Wuhan 430062 |
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| Abstract: | A poly-o-phenylenediamine(PoPD) was synthesised by oxidative polymerisation. The PoPD showed a progressive spontaneous process along the time associated to the doping agent, constituted by HCl, inside the polymeric matrix. The results showed that the PoPD had high conductance of 1.54х10-3S/cm. The PoPD was applied in DSSCs as conductive polymer materials. A photosensitizer of acid blue-7 was used to prepared photoanodes of TiO2/AB7 film. The Voc value of the DSSCs was 0.43V, and the Isc value was 0.378mA/cm2. |
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| Keywords: | Poly-o-phenylenediamine Acid blue-7 Solid-state composite electrolyte |
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