Abstract: | The effect of increases in soil pH by liming on Olsen bicarbonate phosphate (P) test values was investigated using two contrasting New Zealand soils: a highly P retentive Egmont soil and a Tokomaru soil with a low P retention capacity. After incubation with three rates of Ca(OH)2, soil pH was increased, and a reduction in the Olsen P values was observed. The amounts of 32P-exchangeable P, however, increased with increasing soil pH, and there was very little change in water-extractable P. The addition of lime had no significant effect on either the yield or uptake of P by ryegrass grown on the same soils in the glasshouse. It appears that the decline in Olsen P values in soils following liming is a result of an artefact in the Olsen procedure. High concentrations of Ca are involved in the decrease in Olsen P values in limed soils. It is suggested that the precipitation of calcium phosphates in the Olsen extracts of limed soils is responsible for the decrease in the Olsen P values. In a field experiment, increasing soil pH by lime addition also resulted in a decrease in the Olsen P values. |