| Abstract: | The reasonable modulation of tri-s-triazine structure units of g-C3N4 is an effective method to optimize its intrinsic electronic and optical properties, thus boosting its photocatalytic hydrogen-evolution activity. Herein, amino groups are successfully introduced into the tri-s-triazine structure units of g-C3N4 nanosheets to improve their H2-evolution activity via a facile oxalic acid-induced supramolecular assembly strategy. In this case, the resulting amino group-rich porous g-C3N4 nanosheets display a loose and fluffy structure with a large specific surface area (70.41 m2 g?1) and pore volume (0.50 cm3? g??1), and enhanced visible-light absorption (450–800 nm). Photocatalytic tests reveal that the amino group-rich porous g-C3N4 nanosheets (AP-CN1.0 nanosheets) exhibit a significantly elevated photocatalytic H2-production activity (130.7 μmol h?1, AQE = 5.58%), which is much greater than that of bulk g-C3N4 by a factor of 4.9 times. The enhanced hydrogen-generation performance of amino group-rich porous g-C3N4 nanosheets can be mainly attributed to the introduction of more amino groups, which can reinforce the visible-light absorption and work as the interfacial hydrogen-generation active centers to boost the photocatalytic hydrogen production. The present facile and effective regulation of tri-s-triazine structure units may provide an ideal route for the exploitation of novel and highly efficient g-C3N4 photocatalysts. |
