| Abstract: | Silica refractory has excellent high-temperature performance, but its apparent porosity is relatively high. In this work, samples obtained before and after creep testing of silica brick (1550 °C, 50 h), from used silica checker brick (existing only tridymite and amorphous) and from used dome brick (existing only cristobalite and amorphous) were investigated using a three-dimensional structure model based on X-ray computed tomography (CT). The results show that the porosity of silica brick was high but consisted mainly of interconnected pores, with a very small proportion of closed pores (smaller after long-term use). During the use of silica brick, the morphology and phase transformation caused large particles to rupture, and the mineralizer became liquid at high temperature. The broken particles and interconnected pores provided channels for the migration of the liquid in the brick at high temperature. The silica brick presented a homogeneous ceramic structure during long-term operation. Tridymite or cristobalite presented a solid frame leading to an excellent creep performance of the silica brick (the creep rate of the checker brick was ?0.16% at 1550 °C for 50 h). Results were discussed, compared with literature and a model for the transformation of the silica brick from a refractory structure to a homogeneous ceramic structure was established in this paper. |
