Gd-Bi-M-Ce-O (M = Cu,Zr, Ni,Co, Mn) ceria-based solid solutions for low temperature CO oxidation |
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Authors: | Igor V. Zagaynov Ivan V. Shelepin Anatoly A. Konovalov Ekaterina A. Obraztsova Alexander V. Naumkin Alexey V. Bykov Vladimir G. Leontiev |
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Abstract: | Ceria based solid solutions doped by Gd, Bi, and the third dopant were synthesized by the co-precipitation method with ultrasonic treatment, followed by calcination at the temperature of 500°С. Characterization of the synthesized nanosystems by XRD, TEM, TG, Raman spectroscopy, FTIR, XPS was carried out. It is shown that all obtained powders of solid solutions crystallized into a cubic structure of the fluorite type, with an average particle size of 5–15 nm. The samples had a mesoporous structure of the pore diameter of 2–5 nm. The catalytic activity of Gd-Bi-M-Ce-O (M = Cu, Zr, Ni, Co, Mn) solid solutions was carried out. The catalyst Gd0.05Bi0.15Mn0.20Ce0.60O2 has the lowest oxidation temperature. |
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Keywords: | Ceria Solid solution Nanoparticle CO oxidation |
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