Hydrothermal synthesis of micro-flower like morphology aluminum-doped MoS2/rGO nanohybrids for high efficient electromagnetic wave shielding materials

In this study, a three-dimensional (3D) micro-flower like morphology aluminum-doped molybdenum disulfide/reduced graphene oxide (Al@MoS₂/rGO) nanohybrids have been developed using a simple and sensitive hydrothermal approach. Their electromagnetic (EM) parameters (permittivity, permeability) and microwave shielding parameters (S₁₁, S₁₂) have been analyzed and reported for the first time in the microwave frequency range of 8.0–12.0 GHz. It is interesting to note that the electrical conductivity of the nanohybrids increases with the doping concentration of Al-ions, whereas skin-depth has a reverse trend. The 12% Al@MoS₂/rGO nanohybrid shows a higher total electromagnetic interference shielding effectiveness (EMI SE) value about SE_T ~33.38 dB, whereas undoped MoS₂/rGO nanohybrid exhibits a lower value around ~17.07 dB at the same thin thickness. The higher doping concentration of Al-ion creates lattice distortion and crystal defects with high charge carrier mobility between multiple interfaces and at defective sites. Hence, the Al-doping into MoS₂ lattice supported on the rGO surface can greatly enhance EM wave absorption and EMI SE value. The present work suggests that the 12% Al@MoS₂/rGO nanohybrid can be treated as a good microwave absorbing and shielding material and useful in various techno-commercial devices.