| 旋涂-热解法制备WO_3薄膜 |
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| 引用本文： | 杨海涛,尚福亮,高玲,韩海涛.旋涂-热解法制备WO_3薄膜[J].中国钨业,2006,21(5):28-31,36. |
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| 作者姓名： | 杨海涛 尚福亮 高玲 韩海涛 |
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| 作者单位： | 1. 深圳大学,材料学院,深圳市特种功能材料重点实验室,广东,深圳,518060
2. 武汉理工大学,材料复合新技术国家重点实验室,湖北,武汉,430070 |
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| 基金项目： | 教育部科学技术研究重点项目;国家自然科学基金 |
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| 摘 要： | 采用旋涂-热解工艺,以双亲嵌段共聚物F127为软模板剂,合成出WO3薄膜。通过TG-DSC、XRD、SEM等对其热处理温度、晶相组成和显微形貌进行了测试,结果表明所制备的WO3薄膜材料在350℃时主要为非晶WO3,同时含有少量六方晶相,而在500℃时则主要为尺寸在微米极的单斜晶相;电化学循环伏安和光谱测试分析表明该350℃时制备的薄膜具有更好的电致变色性能,对可见光具有较好的调制功能,其最大透过率调制幅度可达55.4%。
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| 关 键 词： | WO_3 薄膜 热处理 电致变色 |
| 文章编号： | 1009-0622（2006）05-0028-04 |
| 收稿时间： | 06 28 2006 12:00AM |
| 修稿时间： | 2006-06-28 |
Preparation of the WO3 Film by the Spin Coating-Pyrolysis Method |
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| YANG Hai-tao,SHANG Fu-liang,GAO Ling,HAN Hai-tao.Preparation of the WO3 Film by the Spin Coating-Pyrolysis Method[J].China Tungsten Industry,2006,21(5):28-31,36. |
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| Authors: | YANG Hai-tao SHANG Fu-liang GAO Ling HAN Hai-tao |
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| Affiliation: | 1.Shenzhen Key Lab of Special Functional Materials, School of Materials, Shenzhen University, Shenzhen 518060, Guangdong, China; 2.State Key Lab of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, Hubei, China |
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| Abstract: | The WO3 film is prepared by the Spin coating-Pyrolysis method with the amphiphilic block copolymer F127 as the soft template.The heat treatment temperature,crystalline phase and microstructure of the WO3 film are tested through the TG-DSC,XRD and SEM techniques respectively.The results shows that the film is in general amorphous WO3 with a little hexagonal WO3 when in 350℃ and monoclinic crystal WO3 in 500℃.It also shows that the mesoporous WO3 film enjoys a good electrochromic performace by the electrochemical cyclic voltammetry and UV-Vis spectrum.The 350℃film possesses excellent modulation to the visible light and the maximal transmittance modulation scope reaches 55.4%. |
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| Keywords: | WO3 |
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