| 乙酰化稻草秸秆的制备及表征 |
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| 引用本文： | 黄凯,张广智,侯秀良,蒋学,黄丹,杨一奇. 乙酰化稻草秸秆的制备及表征[J]. 纤维素科学与技术, 2011, 19(3): 28-34 |
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| 作者姓名： | 黄凯 张广智 侯秀良 蒋学 黄丹 杨一奇 |
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| 作者单位： | 江南大学纺织服装学院,江苏无锡,214122 |
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| 基金项目： | 国家自然科学基金项目,中央高校基本科研业务费专项资金资助项目 |
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| 摘 要： | 通过稻草秸秆与乙酸酐的反应,制备了一种廉价的可降解的乙酰化稻草纤维热塑性材料。利用傅里叶红外光谱(FT-IR),X射线衍射(XRD)、示差扫描量热(DSC)和热重分析(TGA)等分析手段对产物的结构、结晶性能、热学性能等进行了表征。结果显示,当乙酸酐、乙酸的用量分别为秸秆质量的2倍和10倍时,在9%H2SO4催化下,于50℃反应2 h,获得的改性稻草秸秆纤维具有良好的热塑性能。
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| 关 键 词： | 稻草秸秆 纤维素 改性 乙酰化反应 热塑性 |
Preparation and Characterization of Acetylated Rice Straw |
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| HUANG Kai,ZHANG Guang-zhi,HOU Xiu-liang,JIANG Xue,HUANG Dan,YANG Yi-qi. Preparation and Characterization of Acetylated Rice Straw[J]. Journal of Cellulose Science and Technology, 2011, 19(3): 28-34 |
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| Authors: | HUANG Kai ZHANG Guang-zhi HOU Xiu-liang JIANG Xue HUANG Dan YANG Yi-qi |
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| Affiliation: | HUANG Kai1,ZHANG Guang-zhi1,HOU Xiu-liang1,JIANG Xue1,HUANG Dan1,YANG Yi-qi1,2(1.College of Textiles & Clothing,Jiangnan University,Wuxi 214122,China,2.Department of Textiles,Clothing and Design,University of Nebraska-Lincoln,Lincoln 68583-0802,Nebraska,USA) |
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| Abstract: | Inexpensive and biodegradable thermoplastics were developed through acetylation of rice straw. The characterization of acetylated rice straw was performed by Fourier transform infrared （FT-IR）, X-ray diffraction （XRD）, differential scanning calorimetry （DSC） and thermogravimetric analyzer （TGA）. The results showed that the acetylated rice straw got a good thermoplastic when reaction temperature was 50℃, and the reaction time was 2 h, the dosage of H2SO4, glacial acetic acid and acetic anhydride were 9%, 10 and 2 times to one part of rice straw, respectively. |
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| Keywords: | rice straw cellulose modification acetylation thermoplastic |
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