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连续铸造Cu-Cr-Zr合金的时效动力学分析
引用本文:王松,庄滇湘,谢明,张吉明,陈敬超,柳青,周晓龙.连续铸造Cu-Cr-Zr合金的时效动力学分析[J].电工材料,2014(2):13-16.
作者姓名:王松  庄滇湘  谢明  张吉明  陈敬超  柳青  周晓龙
作者单位:[1]昆明贵金属研究所稀贵金属综合利用新技术国家重点实验室,昆明650106 [2]昆明理工大学材料科学与工程学院,昆明650093
基金项目:基金项目:国家自然科学基金项目(51164015、u0837601);国家科技支撑计划项目(2012BAE06805)‘;昆明市科技创新团队项目(20120101AR070005)
摘    要:对经过连续铸造、固溶和冷拉拔的Cu-0.85Cr-0.15Zr合金进行时效处理,研究了时效处理工艺对该合金性能的影响,并对该合金的时效动力学进行了分析。结果表明:Cu-0.85Cr-0.15Zr合金经450℃/3 h时效处理后可以获得较好的综合性能,合金的显微硬度与导电率分别达到237 HV和70.5%IACS。采用相变动力学Avrami经验方程来描述Cu-Cr-Zr合金的时效过程,得到450℃时效时合金的时效动力学方程为f=1-exp(-0.0063t0.802 5),并作出了合金时效时的等温转变动力学"S"曲线。

关 键 词:Cu—Cr-Zr合金  时效处理  动力学  Avrami方程  等温转变

Aging Kinetics Analysis of Cu-Cr-Zr Alloy Prepared by Continuous Casting
WANG Song,ZHUANG Dian-xiang,XIE Ming,ZHANG Ji-ming,CHEN Jing-chao,LIU Qing,ZHOU Xiao-long.Aging Kinetics Analysis of Cu-Cr-Zr Alloy Prepared by Continuous Casting[J].Electrical Engineering Materials,2014(2):13-16.
Authors:WANG Song  ZHUANG Dian-xiang  XIE Ming  ZHANG Ji-ming  CHEN Jing-chao  LIU Qing  ZHOU Xiao-long
Affiliation:1. State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China; 2. College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China)
Abstract:Effects of aging treatment on microstructures and properties of the Cu-0.85Cr-0.15Zr alloy produced by continuous casting, solution treatment and cold drawing process are investigated, and the aging kinetics of the alloy is analyzed. Results show that a better combination of proper- ties is obtained after the Cu-0.85Cr-0.15Zr alloy aged at 450 ℃ for 3 h, consequently the mi- cro-hardness and electrical conductivity of the alloy are 237 HV and 70.5%IACS, respectively. The empirical equation of Avrami phase transformation kinetics is applied to describe the aging process of Cu-Cr-Zr alloy, and the aging kinetics equation at 450 ℃ is given as f=1-exp(-0.0063t0.8025), through which the isothermal transformation kinetics S curve is drawn.
Keywords:Cu-Cr-Zr alloy  aging treatment  kinetics  Avrami formulation  isothermal transformation
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