| 氢等离子体法制备双金属Ni-MoP催化剂 |
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| 引用本文： | 李平. 氢等离子体法制备双金属Ni-MoP催化剂[J]. 工业催化, 2019, 27(4): 76-79. DOI: 10.3969/j.issn.1008-1143.2019.04.014 |
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| 作者姓名： | 李平 |
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| 作者单位： | 银川能源学院 化学与生物工程学院,宁夏 银川,750105 |
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| 基金项目： | 宁夏高等学校科研资助项目(NGY2017252) |
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| 摘 要： | 以磷酸氢二胺和钼酸铵为原料,经氢等离子体法还原制备出单金属MoP及双金属Ni-MoP催化剂。采用XRD和SEM对催化剂进行分析表征;并在固定床反应器内以模拟油为研究对象评价催化剂活性。结果表明,双金属Ni-MoP催化剂的活性高于单金属MoP催化剂,二苯并噻吩转化率达到26.21%,联苯选择性达35.61%,环己烷基苯选择性达19.96%。
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| 关 键 词： | 催化化学 氢等离子 磷化钼 Ni-MoP催化剂 加氢脱硫 |
Preparation of bimetallic Ni-MoP catalyst by hydrogen plasma |
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| Li Ping. Preparation of bimetallic Ni-MoP catalyst by hydrogen plasma[J]. Industrial Catalysis, 2019, 27(4): 76-79. DOI: 10.3969/j.issn.1008-1143.2019.04.014 |
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| Authors: | Li Ping |
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| Affiliation: | School of Chemical and Biological Engineering,Yinchuan University of Energy,Yinchuan 750105,Ningxia,China |
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| Abstract: | MoP and Ni-MoP catalysts were prepared by hydrogen plasma reduction using hydrogen diamine phosphate and ammonium molybdate as raw material.The catalyst was characterized by XRD and SEM,and evaluated in a fixed-bed reactor with simulated oil used as research object.The results showed that the activity of modified Ni-MoP catalyst was higher than MoP catalyst.The conversion of dibenzothiophene was 26.21%,selectivity of biphenyl and cyclohexalkylbenzene were 35.61% and 19.96% reapectively. |
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| Keywords: | catalysis chemistry hydrogen plasma molybdenum phosphide hydrodesulfurization |
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