| Abstract: | New solid state epoxy resins based on diglycidyl ether of 1,1‐dichloro‐2,2 bis (4‐hydroxyphenyl), ethylene (BPC) and BPA epoxy resins in the reaction with BPC and BPA were developed. Solid epoxy resins were synthesised by the use of two different heating methods: conventional and microwave reactor. The use of microwave radiation as novel heating medium as an alternative to the conventional methods, which provide a quicker and more effective synthesis. The solid epoxies have high melting points higher than 100°C and the polycondensation degree remains between n = 4–12. Epoxy value stays low and occurs around 0,02–0,1. BPA epoxy resins and diglycidylether of BPC II were compared in terms of reaction speed. It can be seen that the reaction of BPC diglycidylether occurs approximately 20% quicker given the same reaction conditions of temperature, and balance of catalyst. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3850–3854, 2006 |
