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苛化法再生乙烯生产中的废碱液
引用本文:余政哲,孙德智,杜龙弟,段晓东,史鹏飞,李长海. 苛化法再生乙烯生产中的废碱液[J]. 石油化工, 2003, 32(6): 517-520
作者姓名:余政哲  孙德智  杜龙弟  段晓东  史鹏飞  李长海
作者单位:哈尔滨工业大学,环境科学与工程系,黑龙江,哈尔滨,150001
摘    要:采用苛化技术对乙烯生产中的废碱液进行了再生研究,考察了影响再生效果的各种条件因素。当苛化反应温度大于80℃、反应时间超过2h、n(CaO)/n(Na2CO3)=1 1/1时,Na2CO3的转化率可在90%以上,并且再生碱液的物理性质以及再生碱液对CO2吸收速率与新鲜碱液基本相同。

关 键 词:苛化  废碱液  乙烯裂解  再生
文章编号:1000-8144(2003)06-0517-04
修稿时间:2003-01-06

Regeneration of Spent Caustic from Ethylene Plant by Cauticization
Abstract:Causticization was adopted to regenerate spent caustic of ethylene plant Various conditions which affect regeneration efficiency, such as reaction temperature, reaction time, and stoichiometric ratio of CaO and Na2CO3, were investigated When temperature of causticization was higher than 80 ℃, reaction time over 120 min, and stoichiometric ratio 11/1, causticizing conversion was above 90% Regenerated caustic had approximately the same physical properties and adsorption rate of CO2 as fresh caustic
Keywords:cauticization  spent caustic  ethylene cracking plant  regeneration
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