| 双金属氰化络合物(DMC)催化剂的合成及应用研究进展 |
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| 引用本文： | 王文浩,李俊贤,周集义,张兴英.双金属氰化络合物(DMC)催化剂的合成及应用研究进展[J].化学推进剂与高分子材料,2004,2(5):5-9. |
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| 作者姓名： | 王文浩 李俊贤 周集义 张兴英 |
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| 作者单位： | 黎明化工研究院,河南洛阳,471001;北京化工大学,北京,100029 |
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| 摘 要： | 从催化剂的结构、制备工艺、配位体等方面讨论了催化剂合成、催化机理和低不饱和度聚醚的制备方法的研究进展。催化剂的制备工艺及小分子配位体的加入顺序影响催化剂的晶体结构和催化剂的活性。配位体的类型对催化剂活性有显著影响,寻找更有效的配位体是提高催化剂性能的有效途径。
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| 关 键 词： | 双金属氰化物络合物催化剂 低不饱和度聚醚多元醇 配位体 |
| 文章编号： | 1672-2191(2004)05-0005-05 |
| 修稿时间： | 2004年7月18日 |
Progress of Synthesis and Application of Double Metal Cyanide Complex Catalysts(DMC) |
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| WANG Wen-hao,LI Jun-xian,ZHOU Ji-yi,ZHANG Xing-ying.Progress of Synthesis and Application of Double Metal Cyanide Complex Catalysts(DMC)[J].Chemical Propellants & Polymeric Materials,2004,2(5):5-9. |
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| Authors: | WANG Wen-hao LI Jun-xian ZHOU Ji-yi ZHANG Xing-ying |
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| Affiliation: | WANG Wen-hao1,LI Jun-xian1,ZHOU Ji-yi1,ZHANG Xing-ying2 |
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| Abstract: | In respects of catalyst structure, preparation process, complex bodies etc., synthesis of the catalysts and their catalyticmechanism as well as progress in preparation methods of low unsaturated degree polyether polyols were discussed. The preparationtechnology of catalyst and addition orders of small molecular complex bodies influence crystal structure and activity of the catalystsmarkedly. Using more effective complex bodies will be effective approach for advancing performance of the catalysts. |
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| Keywords: | double metal cyanide complex catalysts low unsaturated degree polyether polyols complex bodies |
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