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沸石负载TiO_2光催化降解性能研究
引用本文:王卫东,黄章勇,张乃军,林峰,高影.沸石负载TiO_2光催化降解性能研究[J].吉林化工学院学报,2010,27(3):4-7.
作者姓名:王卫东  黄章勇  张乃军  林峰  高影
作者单位:1. 吉林化工学院化工与材料工程学院,吉林,吉林,132022
2. 巴斯夫新戊二醇有限公司技术科,吉林,吉林,132002
3. 中国石油吉林石化分公司化肥厂,吉林,吉林,132021
4. 吉化集团农药化工有限公司,吉林,吉林,132021
摘    要:以钛酸正四丁酯为原料、无水乙醇为溶剂、40~60目人造沸石为载体,采用溶胶-凝胶法制备负载型TiO2光催化剂.利用40 W(λ=253.7 nm)紫外线杀菌灯为光源的自制反应器进行光催化氧化实验.结果表明,当亚甲基蓝染料的初始浓度为15 mg/L,样品的煅烧温度为400℃,pH=2,催化剂的投加量为2.5 g/L,反应时间2.5 h,脱色率达80%以上.

关 键 词:二氧化钛  人造沸石  光催化降解  亚甲基蓝

Study on the properties of photocatalytic degradation with immobilized titanium dioxide
WANG Wei-dong,HUANG Zhang-yong,ZHANG Nai-jun,LIN Feng,GAO Ying.Study on the properties of photocatalytic degradation with immobilized titanium dioxide[J].Journal of Jilin Institute of Chemical Technology,2010,27(3):4-7.
Authors:WANG Wei-dong  HUANG Zhang-yong  ZHANG Nai-jun  LIN Feng  GAO Ying
Affiliation:1.College of Chemical and Material Engineering,Jilin Institute of Chemical Technology,Jilin City 132022,China;2.BASF JCIC Neopentylglycol Company Ltd.,Jilin City 132021,China;3.Fertilizer Plant,Jilin PetroChemical Company,Jilin City 132021,China;4.Pesticide Chemical Company,Jilin Chimcal Group Corporation,Jilin City 132021,China)
Abstract:With using Ti(OBu)4 as material,anhydrous ethanol as solvent,artificial zeolite(mesh for 40~60) as the carrier,the immobilized TiO2 photocatalyst was prepared by Sol-Gel technique.The photocatalytic oxidation experiment was implemented in a self-made reactor whose light resource is from the 40 W(253.7nm) ultraviolet radiation antiseptic lamp.The result indicates that the decoloration rate can reach over 80% when the initial concentration of the methylene blue is 15 ml/L,the heating temperature is 450 ℃,PH is about 2,the adding amount of catalyst is about 2.5 g/L and the reaction time is 2.5 h.
Keywords:TiO2  artificial zeolite  photocatalytic degradation  methylene blue
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