Ligand transfer between hard and soft metal centres. Synthesis and X-ray characterisation of a new trinuclear Pd(II) dithiocarbamate Pd3(Et2NCS2)4Cl2 |
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| Affiliation: | 1. Department of Physics, Manonmaniam Sundaranar University, Tirunelveli 627 012, Tamil Nadu, India;2. Department of Chemistry, Manonmaniam Sundaranar University, Tirunelveli 627 012, Tamil Nadu, India |
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| Abstract: | Reaction between PdCl2(PhCN)2 and Nb2(μ-S2)2(Et2NCS2)4 results in a transfer of the dithiocarbamate ligand from Nb(IV) to Pd(II) and allows isolation of the new trinuclear palladium complex Pd3(Et2NCS2)4Cl2 for the first time. The crystal structure of the complex has been determined. |
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