| 增韧改性环氧树脂互穿网络聚合物的合成与表征 |
| |
| 引用本文： | 吕忠达,徐爱敏,国建飞,张桓,杨小刚. 增韧改性环氧树脂互穿网络聚合物的合成与表征[J]. 涂料工业, 2011, 41(10): 5-8 |
| |
| 作者姓名： | 吕忠达 徐爱敏 国建飞 张桓 杨小刚 |
| |
| 作者单位： | 1. 宁波市高等级公路建设指挥部,浙江宁波,315192
2. 中国科学院海洋研究所腐蚀中心,山东青岛,266071 |
| |
| 摘 要： | 合成了端异氰酸酯/环氧丙烯酸树脂互穿网络聚合物,在环氧树脂交联网络中引入柔性链段,达到增韧的目的。通过改变端异氰酸酯和环氧丙烯酸树脂的组分比,合成不同组成的互穿网络聚合物(IPNs)。借助红外光谱和扫描电镜等分析方法,研究了IPNs的分子混合形态结构。同时采用差热分析法(DSC)测试了聚合物的玻璃化转变温度,结果表明:端异氰酸酯预聚体含量越高,聚合物的玻璃化转变温度越低。对成膜物的力学性能研究表明,INPs的拉伸强度在端异氰酸酯/环氧丙烯酸树脂比例为30:70时,拉伸强度为55.24 MPa,是纯环氧树脂的2.5倍。
|
| 关 键 词： | 环氧丙烯酸树脂 互穿网络聚合物 柔性链段 |
Synthesis and Characterization of Modified Epoxy Resin Interpenetrating Polymer Networks |
| |
| Lv Zhongda,Xu Aimin,Guo Jianfei,Zhang Huan,Yang Xiaogang. Synthesis and Characterization of Modified Epoxy Resin Interpenetrating Polymer Networks[J]. Paint & Coatings Industry, 2011, 41(10): 5-8 |
| |
| Authors: | Lv Zhongda Xu Aimin Guo Jianfei Zhang Huan Yang Xiaogang |
| |
| Affiliation: | Lv Zhongda~1,Xu Aimin~1,Guo Jianfei~1,Zhang Huan~1,Yang Xiaogang~2 (1.Ningbo Highway Construction Headquarters,Ningbo,Zhejiang 315192,China,2.Institute of Oceanology,Chinese Academy of Sciences,Qingdao,Shandong 266071,China) |
| |
| Abstract: | The interpenetrating polymer networks(IPNs) based on isocyanine/epoxy acrylate resin was synthesized.The toughness of the epoxy resin was enhanced by introducing flexible chain in the interpenetrating networks.IPNs with different composition were prepared by changing the mass ratio of isocyanate and epoxy acrylate resin.The molecular morphology of IPNs was characterized by SEM and FT - IR.The results of differential scanning calorimetry(DSC) showed that the glass transition temperature decreased with increa... |
| |
| Keywords: | epoxy acrylate resin interpenetrating polymer flexible chain |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
