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BOPP专用树脂的流变行为研究
引用本文:李广全,段宏义,刘敏,邵月君,闫功臣.BOPP专用树脂的流变行为研究[J].广州化工,2014(16):45-46,85.
作者姓名:李广全  段宏义  刘敏  邵月君  闫功臣
作者单位:中国石油兰州化工研究中心;中国石油华南化工销售分公司
基金项目:中国石油科学研究与技术开发基金项目(No:2012B-2703-0315)
摘    要:利用高压毛细管流变仪,对三种不同BOPP专用树脂的流变性能进行测定,BOPP专用料均表现为剪切应力随剪切速率增加而增加,但增加速率明显减弱,表观粘度随剪切速率增加而减小的特点,具有明显的假塑性的流动行为。通过分析温度、剪切速度和分子量及其分布对树脂的表观粘度的影响,确定不同树脂改善熔体粘度最有效的方法。

关 键 词:BOPP  流变性能  分子量及其分布  表观粘度

Study on theRheological Behavior of BOPP
LI Guang-quan;DUAN Hong-yi;LIU Min;SHAO Yue-jun;YAN Gong-chen.Study on theRheological Behavior of BOPP[J].GuangZhou Chemical Industry and Technology,2014(16):45-46,85.
Authors:LI Guang-quan;DUAN Hong-yi;LIU Min;SHAO Yue-jun;YAN Gong-chen
Affiliation:LI Guang-quan;DUAN Hong-yi;LIU Min;SHAO Yue-jun;YAN Gong-chen;Lanzhou Petrochemical Research Center,PetroChina;Petrochina South China Chemicals Marketing Company;
Abstract:Using high pressure capillary rheometer , the rheological properties of three kinds of special resin biaxial oriented polypropylene ( BOPP) were determined , the special material BOPP displayed for the shear stress increases with the shear rate increased , but the increasing rate decreased with shear rate , apparent viscosity increased , with obvious pseudoplastic flow behavior.Based on the analysis of influence of temperature , shear rate and the molecular weight and distribution of resin viscosity , the different resin melt viscosity was determine of the most effective methods to improve.
Keywords:BOPP  rheological property  molecular weight (Mw) and weight distribution ( Mw distribution )  apparent viscosity
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