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Crystal structure and microwave dielectric properties of garnet-type Ca2YZr2-xTixAl3O12 ceramics for dual-band bandpass filters
Affiliation:1. School of Optical and Electronic Information, Key Lab of Functional Materials for Electronic Information (B) of MOE, Huazhong University of Science and Technology, Wuhan 430074, China;2. Wenzhou Institute of Advanced Manufacturing Technology, Huazhong University of Science and Technology, Wenzhou 325000, China;3. Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China;4. State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China;1. State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054, China;2. Jiangxi Guo Chuang Industrial Park Development Co., Ltd., Ganzhou 341000, China;1. Laboratory of Thin Film Techniques and Optical Test, Xi''an Technological University, Xi’an 710032, Shaanxi, China;2. Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education & International Center for Dielectric Research, School of Electronic and Information Engineering, Xi’an Jiaotong University, Xi''an 710049, China;1. Guangxi Key Laboratory of Optical and Electronic Materials and Devices, College of Material Science and Engineering, Guilin University of Technology, Guilin, 541004, China;2. Guangxi Universities Key Laboratory of Non-Ferrous Metal Oxide Electronic Functional Materials and Devices, College of Material Science and Engineering, Guilin University of Technology, Guilin, 541004, China;3. College of Material Science and Engineering, Baise University, Baise, 533000, China
Abstract:Microwave dielectric ceramics with a high-quality factor are vital materials for substrates, dielectric resonators, and filters in millimeter-wave communication systems. Here, a novel microwave dielectric ceramic based on a garnet-type Ca2YZr2Al3O12 compound for bandpass filter was prepared using the solid-state reaction method. Sintering the Ca2YZr2Al3O12 ceramics at 1600 ℃ for 5 h resulted in excellent microwave dielectric properties of εr = 10.81 ± 0.16, Qf = 87,628 ± 4000 GHz and τf = ?34.3 ± 0.5 ppm/℃. Increasing the Ti4+ content of the Ca2YZr2-xTixAl3O12 ceramics significantly improved the sintering process. Superior microwave dielectric properties (εr = 11.93 ± 0.15, Qf = 121,930 ± 2600 GHz and τf = ?30.8 ± 0.4 ppm/℃) were obtained for Ca2YZr2-xTixAl3O12 (x = 0.3) because of its dense microstructure, large grain size and high lattice energy. The Ca2YZr2-xTixAl3O12 (x = 0.3) ceramics were used to fabricate a dual-band bandpass filter with a hairpin structure that exhibited a large return loss (|S11| > 12 dB) and a small insertion loss (|S21| < 0.73 dB). The high performance of the Ca2YZr2-xTixAl3O12 ceramics and the corresponding bandpass filter makes this material a potential candidate for millimeter-wave devices.
Keywords:Microwave dielectric properties  Garnet
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