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The birth of copper-red glaze: Optical property and firing technology of the glaze from Changsha Kiln (8th–9th century)
Affiliation:1. Department of Conservation Science, The Palace Museum, Beijing, China;2. Key Research Base of Ancient Ceramics, The Palace Museum, Beijing, China;3. Hunan Provincial Institute of Cultural Relics and Archaeology, Changsha, China;1. School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, 333001, PR China;2. State Key Lab of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, 100084, Beijing, PR China;3. Materials Engineering, The University of Queensland Brisbane, St Lucia, QLD 4072, Australia;1. CNRS, CEMES, Toulouse University, 31055 Toulouse, France;2. Institute of Silicate Cultural Heritage, School of Material Science and Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, 710021 Xi’an, China;1. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China;2. Key Scientific Research Base of Ancient Ceramics, State Administration for Cultural Heritage, Shanghai, 201899, China;3. Key Laboratory of the Comprehensive Analysis Technology for Ancient Ceramics and its Applications, Ministry of Culture and Tourism, Shanghai, 201899, China;4. University of Chinese Academy of Sciences, Beijing, 100049, China
Abstract:Changsha Kiln rose and flourished alongside the development of China's Maritime Silk Road (8th–9th century). The kiln occupies an important place in the development of China's ceramic science and technology, notably as the source of high-temperature copper-red glaze. A variety of lime-colored glaze was one product of Changsha Kiln. Its surface was decorated with both copper-green and copper-red, and is the earliest known example of the successful firing of a copper-red glaze. This ware is representative of the birth of high-temperature copper-red glaze, but there has been a lack of research on its optical properties and the technology’s origin. In this paper, OM, SEM, TEM, optical coherence tomography (OCT), XRF, fiber optic spectrometry, and other analytical techniques were used to investigate the red and green glazes of Changsha Kiln. The key result of this paper is to reveal the optical properties of copper-green and copper-red in combination with colloidal absorption, ion absorption, and scattering, and to study the key factors for the origin of the high-temperature copper red glaze.
Keywords:Changsha Kiln  Copper-red  Optical property  Ceramic technology
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