| 具有光电导性能的聚合物的合成 |
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| 引用本文： | 荣宇. 具有光电导性能的聚合物的合成[J]. 山东化工, 1999, 0(3): 10-12,20 |
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| 作者姓名： | 荣宇 |
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| 作者单位： | 山东省化工研究院 |
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| 摘 要： | 本研究首先合成了带氨基的酞菁锰，并使之成为重氮盐，通过重氮偶合法首次合成了含酞菁锰乙烯基咔唑单体，使之分别与丙烯腈、４－乙烯基吡啶发生共聚，合成出酞菁锰单体接枝率不同的共聚物Ｉ、Ⅱ，经ＩＲ、ＵＶ／ｖｉｓ、原子吸收法表征确证了聚合物和单体的结构，聚合物Ｉ、Ⅱ均具有良好的溶解性、成膜性。把聚合物Ｉ、Ⅱ及酞菁锰作为光生材料与ＴＰＤ、ＴＰＡ、吡唑啉匹配后制成功能分离型的双层光电导体。讨论了它们的光电导性，
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| 关 键 词： | 酞菁 乙烯基咔唑 光电导性 高聚物 合成 |
The Synthesis of Photoconductive Polymer |
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| Rong Yu. The Synthesis of Photoconductive Polymer[J]. Shandong Chemical Industry, 1999, 0(3): 10-12,20 |
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| Authors: | Rong Yu |
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| Abstract: | Mn-dinitro-diamine phthalocyanine was synthesized first,and then its corvesponding diazonium salt was obtained.Manganese-phthalocyanine appended vinylcarbazole was synthesized by diazocoupling reaction.The monomer was radical copolymerized with acrylonitrile and 4-vinylpyzidin.The chemical structures of monomer and polymers were identified by IR,UV/vis,atomic absorption spectrophotometer,etc.Polymer ,have good solubility.Double layered photoreceptor device (P/R) were made where polymer , and monomer were used as charge-generation-materials(CGM),tetraphenyl benzidine (TPD) or triphenylamine (TPA) or pyrazoline were used as charge-transportation-materials (CTM) These photoconductive properties were discussed.The results indicated that polymers showed better photoconductivity than monomer. |
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| Keywords: | phthalocyanine vinylcarbazole photoconductive |
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