| 二环[2.2.1]/[2.2.2]庚烷二羧酸盐成核剂研究及应用进展 |
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| 引用本文： | 史建公,张敏宏,赵桂良,刘志坚,石勤智,赵丽梅,杨万泰. 二环[2.2.1]/[2.2.2]庚烷二羧酸盐成核剂研究及应用进展[J]. 合成材料老化与应用, 2011, 0(4): 46-52 |
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| 作者姓名： | 史建公 张敏宏 赵桂良 刘志坚 石勤智 赵丽梅 杨万泰 |
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| 作者单位： | 中国石化催化剂分公司博士后科研工作站;中国石化催化剂北京燕山分公司;中国石化催化剂分公司;中国石化北京燕山分公司树脂应用研究所;北京化工大学材料科学与工程学院; |
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| 摘 要： | 二环[2.2.1]庚烷二羧酸盐和二环[2.2.2]庚烷二羧酸盐是重要的分散型聚丙烯成核剂,HPN-68是最优秀的商业化产品。该类成核剂最大的特点是可以提高聚丙烯的结晶温度和改性PP收缩的各向同性。详细介绍了该类成核剂的结构、制备方法和在聚丙烯中的应用。
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| 关 键 词： | 成核剂 二环[2.2.1]庚烷二羧酸盐 二环[2.2.2]庚烷二羧酸盐 聚丙烯 |
Research and Application Advances in Biocyclo[2.2.1]/[2.2.2]Heptane Dicarboxylate Salts as Polyolefin Nucleators |
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| SHI Jian-gong,,ZHANG Min-hong,ZHAO Gui-liang ,LIU Zhi-jian , SHI Qin-zhi,,ZHAO Li-mei ,,YANG Wan-tai,,Beijing , Beijing Yanshan Branch Company of SCC,.Sinopec Catalyst Company,Beijing , Resin Application Research Institute of Sinopec Bejing Yanshan Branch Company,Beijing , College of Materials Science , Engineering,Beijing University of Chemical Technology,Beijing ). Research and Application Advances in Biocyclo[2.2.1]/[2.2.2]Heptane Dicarboxylate Salts as Polyolefin Nucleators[J]. Synthetic Materials Aging and Application, 2011, 0(4): 46-52 |
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| Authors: | SHI Jian-gong ZHANG Min-hong ZHAO Gui-liang LIU Zhi-jian SHI Qin-zhi ZHAO Li-mei YANG Wan-tai Beijing Beijing Yanshan Branch Company of SCC .Sinopec Catalyst Company Beijing Resin Application Research Institute of Sinopec Bejing Yanshan Branch Company Beijing College of Materials Science Engineering Beijing University of Chemical Technology Beijing ) |
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| Affiliation: | SHI Jian-gong1,2,ZHANG Min-hong1,ZHAO Gui-liang 1,LIU Zhi-jian 1,3 SHI Qin-zhi1,3,ZHAO Li-mei 1,4,YANG Wan-tai1,5(1 Post-doctoral Research Station of Sinopec Catalyst Company(SCC),Beijing 102400,2 Beijing Yanshan Branch Company of SCC,3.Sinopec Catalyst Company,Beijing 100011,4 Resin Application Research Institute of Sinopec Bejing Yanshan Branch Company,Beijing 102500,5 College of Materials Science and Engineering,Beijing University of Chemical Technology,Beijing 100029) |
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| Abstract: | Biocycloheptane[2.2.1] dicarboxylate and biocyclo[2.2.2]heptane dicarboxylate salts are very important dispersive-type nucleating agents for polypropylene(PP),and HPN-68 is one of the most outstanding commercial products.Such nucleating agent can increase the crystallization temperature of and keep PP isotropic shrinkage.The structures,preparation methods,and uses in PP were reviewed in detail. |
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| Keywords: | nucleating agent biocyclo[2.2.1]heptane dicarboxylate salt biocyclo[2.2.2]heptane dicarboxylate salt polypropylene |
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