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氢在钢中晶格间隙和氢陷阱之间的扩散模式
引用本文:王征,王禹华,李连杰,陈觉之. 氢在钢中晶格间隙和氢陷阱之间的扩散模式[J]. 材料开发与应用, 2009, 24(4): 85-89
作者姓名:王征  王禹华  李连杰  陈觉之
作者单位:1. 武汉海军工程大学船舶与动力学院,湖北,武汉,430033
2. 海军驻洛阳407厂军事代表室,河南,洛阳,471039
3. 海军指挥学院信息系,江苏,南京,211800
摘    要:氢在晶格间隙和陷阱点的扩散包括:氢在晶格间隙之间的扩散,氢从晶格间隙扩散到陷阱点,氢从陷阱点逃逸到晶格间隙的过程。本文运用气体在金属中的扩散理论,分析了氢在钢中晶格间隙和氢陷阱之间的扩散模式,以及通过扩散在两者之间建立的平衡状态。氢陷阱中氢浓度随时间的变化率等于晶格间隙的氢扩散到陷阱点引起的氢浓度变化率减去陷阱点中氢逃逸到晶格间隙引起的氢浓度变化率,其数学关系式符合McNabb和Foster建立的氢陷阱模型。氢在晶格间隙和陷阱点之间的平衡,实质是氢在晶格间隙的化学势μL和氢在陷阱点的化学势μT之间达到局部平衡,氢在陷阱中的占据分数很低的情况下(θT《1),氢的有效扩散系数Deff的表达式是与陷阱结合能EB有关的温度函数。

关 键 词:  晶格间隙  氢陷阱  扩散模式

Hydrogen diffusion Models between Lattice Interstitial Sites and Hydrogen Trapping Sites in the Steel
WANG Zheng,WANG Yu-hua,LI Lian-jie,CHEN Jue-zhi. Hydrogen diffusion Models between Lattice Interstitial Sites and Hydrogen Trapping Sites in the Steel[J]. Development and Application of Materials, 2009, 24(4): 85-89
Authors:WANG Zheng  WANG Yu-hua  LI Lian-jie  CHEN Jue-zhi
Affiliation:WANG Zheng1,WANG Yu-hua2,LI Lian-jie1,CHEN Jue-zhi3 (1.College of Naval Architecture & Power,Naval University of Engineering,Wuhan 430033,China,2.Naval Military Delegation Room of 407 Factory,Luoyang 471039,3.Information Department of Naval Comm, College,Nanjing 211800,China)
Abstract:Various hydrogen trapping sites exist in the steel which can dissolve the hydrogen and decrease the diffusing hydrogen.To investigate the effect of trapping sites on the hydrogen distribution,hydrogen diffusion models and the equilibrium states between the lattice interstitial sites and the hydrogen trapping sites were analyzed by using the theory of gas diffusing in the metal.Hydrogen concentration changing rate with respect to time is equate to the changing rate of hydrogen diffusing from lattice intersti...
Keywords:Hydrogen  Lattice interstitial site  Hydrogen trapping  Diffusion model  
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