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Miscible blends of a vinylidene chloride/vinyl chloride copolymer with aliphatic polyesters
Authors:E M Woo  J W Barlow  D R Paul
Abstract:A copolymer of vinylidene chloride and vinyl chloride containing 13.5% by weight of the latter has been solution blended with four aliphatic polyesters: poly(?-caprolactone), poly(2,2-dimethyl-1,3-propylene adipate), poly(1,4-cyclohexanedimethylene succinate), and poly(2,2-dimethyl-1,3-propylene succinate). Each blend was examined visually and by differential scanning calorimetry. All blends with the copolymer form a single miscible amorphous phase at all compositions and all temperatures except for the latter mentioned polyester, which exhibits liquid–liquid phase separation at temperatures above a measured cloud point curve. Information about interactions between the components in each blend is estimated from melting point data and discussed.
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