Oxygen permeation properties of BSCF5582 tubular membrane fabricated by the slip casting method

BSCF5582 tubular oxygen separation membranes were prepared using the most cost effective slip casting techniques. The optimum slurry composition was identified and a dense, and crack free 60 mm long BSCF5582 tubular membrane being successfully prepared after the programmed sintering process. The effects of the feed flow rate and the sweeping flow rate on the oxygen permeation flux of the tubular BSCF5582 membrane were investigated. The oxygen permeation flux increased with an increase of the oxygen chemical potential gradient to a maximum of 42.5 cm³/min in an O₂/N₂ condition at 1223 K for the 1.5 mm thick, 60 mm long BSCF tube, a value which corresponds to 1.42 cm³/min cm². The ionic conductivity of the oxygen was successfully calculated in the dominant electron conducting regime. The ionic conductivity was found to increase with an increase of the temperature to 900 °C, indicating that it is a thermally activated process with an activation energy of 0.70 ± 0.1 eV in an air environment.