The adsorption feature and photocatalytic oxidation activity of K1?2xMxTiNbO5 (M = Mn,Ni) for methyl mercaptan in methane |
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Authors: | Weimeng Cai Guohui Lu Jie He Yunxiang Lan |
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Affiliation: | School of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, PR China |
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Abstract: | The novel photocatalytic ceramics material K1?2xMxTiNbO5 (M = Mn, Ni) were prepared through Mn2+ and Ni2+ ion-exchange of KTiNbO5, which was synthesized by a hydrothermal method. The influence of the ion-exchange process on the structure and morphology of prepared ceramics material were investigated by such physicochemical methods as powder X-ray diffraction (XRD), scanning electron microscope (SEM), high-resolution transmission electron microscope (HRTEM), UV–visible diffuse reflectance spectroscopy (UV–vis DRS) and Fourier-transform infrared (FT-IR) microscopy. The adsorption and photocatalytic oxidation of methyl mercaptan (MM) in methane were used to evaluate the catalytic performance of different constitutes. The results revealed that K1?2xNixTiNbO5 exhibited better adsorption and photocatalytic oxidation activity for MM in methane under both visible and UV light radiation. While the photocatalytic oxidation activity of K1?2xMnxTiNbO5 is similar to that of K1?2xNixTiNbO5, however it has little adsorption activity for MM in dynamic state. |
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