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1-(5-萘酚7-磺酸)-3-[4-(苯基偶氮)苯基]-三氮烯-溴化十四烷基吡啶- 阴离子表面活性剂显色反应研究
引用本文:冯泳兰,邝代治. 1-(5-萘酚7-磺酸)-3-[4-(苯基偶氮)苯基]-三氮烯-溴化十四烷基吡啶- 阴离子表面活性剂显色反应研究[J]. 化学试剂, 2003, 25(6): 353-354,356
作者姓名:冯泳兰  邝代治
作者单位:衡阳师范学院,化学系,湖南,衡阳,421008;衡阳师范学院,化学系,湖南,衡阳,421008
基金项目:湖南省自然科学基金资助课题(01JY2078),湖南省教育厅重点资助课题(01A029).
摘    要:介绍了在NaOH介质中,阳离子表面活性剂溴化十四烷基吡啶(TPB)存在下,1—(5—萘酚—7—磺酸)—3—[4—(苯基偶氮)苯基]—三氮烯(NASAPAPT)与阴离子表面活性剂(AS)的显色反应。该显色反应显色快,稳定,显色配合物最大吸收位于594nm,显色剂与阴离子表面活性剂配合比为1:3。研究的方法用于实样分析。

关 键 词:1-(5-萘酚-7-磺酸)-3-[4-(苯基偶氮)苯基]-三氮烯  溴化十四烷基吡啶  阴离子表面活性剂  显色反应
文章编号:0258-3283(2003)06-0353-02

Study on the color reaction of 1-(5-naphthol-7-sulfonic acid)-3-(4-phenyl-azophenyl)triazene with tetradecylpyridinium bromide and anionic surfactants
FENG Yong-lan,KUANG Dai-zhi. Study on the color reaction of 1-(5-naphthol-7-sulfonic acid)-3-(4-phenyl-azophenyl)triazene with tetradecylpyridinium bromide and anionic surfactants[J]. Chemical Reagents, 2003, 25(6): 353-354,356
Authors:FENG Yong-lan  KUANG Dai-zhi
Abstract:This paper reports the new color reaction of 1-(5-naphthol-7-sulfonic acid)-3-( 4-phenylazophenyl) tri-azene ( NASAPAPT) with tetradecylpyridinium bromide (TPB) and anionic surfactant (AS) in NaOH basic medium. The color reaction was fast and stable. The maximum absorption wavelength of the complex was 594nm. The molar composition of the complex was found to be NASA-PAPT:AS=1:3.The method has been applied to analysis of water sample with satisfactory results.
Keywords:1-(5-naphthol-7-sulfonic acid)-3-(4-phenylazo-phenyl) triazenet tetradecylpyridinium bromide) anionic surfactants  colour reaction
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