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基于团簇和胶粘原子模型的(Fe-Ni)-B-Y-Nb块体非晶合金
引用本文:陈伟荣,韩 光,陈季香,朱春雷,王 清,王英敏,董 闯. 基于团簇和胶粘原子模型的(Fe-Ni)-B-Y-Nb块体非晶合金[J]. 稀有金属材料与工程, 2011, 40(2): 236-238
作者姓名:陈伟荣  韩 光  陈季香  朱春雷  王 清  王英敏  董 闯
作者单位:1. 大连大学,辽宁,大连,116622
2. 大连大学,辽宁,大连,116622;大连理工大学,辽宁,大连,116024
3. 大连理工大学,辽宁,大连,116024;大连海事大学,辽宁,大连,116026
4. 大连理工大学,辽宁,大连,116024
基金项目:辽宁省教育厅高校科研项目(2008030);国家自然科学基金资助项目(50671018,50631010,50401020)
摘    要:应用团簇+胶粘原子模型在三元Fe-B-Y合金系中设计三元合金成分,选择最密堆的CN10Archimedes八面体反棱柱Fe8B3作为基本团簇,Y为胶粘原子。在此基础上添加3at%Nb作为微合金化元素形成四元合金。以适量的Ni替换Fe,形成五元合金[(Fe100-xNix)8B3-Y]97-Nb3。结果表明,当Ni的含量小于30at%时,均可形成直径为2mm的块体非晶合金,其中,合金[(Fe94Ni6)8B3-Y]97-Nb3具有最大的Tg、Tx和Trg值,分别为:884K、972K和0.634。

关 键 词:团簇  胶粘原子  Fe基块体非晶合金
收稿时间:2010-03-11

(Fe-Ni)-B-Y-Nb Bulk Metallic Glasses Based on the Model of Clusters and Glue Atoms
Chen Weirong,Han Guang,Chen Jixiang,Zhu Chunlei,Wang Qing,Wang Yingmin and Dong Chuang. (Fe-Ni)-B-Y-Nb Bulk Metallic Glasses Based on the Model of Clusters and Glue Atoms[J]. Rare Metal Materials and Engineering, 2011, 40(2): 236-238
Authors:Chen Weirong  Han Guang  Chen Jixiang  Zhu Chunlei  Wang Qing  Wang Yingmin  Dong Chuang
Affiliation:Dalian University, Dalian 116622, China;Dalian University, Dalian 116622, China;Dalian University of Technology, Dalian 116024, China;Dalian University of Technology, Dalian 116024, China;Dalian University of Technology, Dalian 116024, China;Dalian University of Technology, Dalian 116024, China;Dalian University of Technology, Dalian 116024, China
Abstract:Using the model of cluster + glue atom, the ternary bulk metallic glasses (BMG) in Fe-B-Y system was designed, choosing the close-packed Archimedes octahedral antiprism CN-10 Fe8B3 as basic cluster and Y as glue atom. 3at%Nb was added as minor alloying element to form quaternary BMG. Ni was used to substitute for Fe, and a quinary BMG, [(Fe100-xNix)8B3-Y]97-Nb3, was formed. Results show that when Ni is less than 30at% the BMG with diameter of 2 mm can be obtained and the alloy [(Fe94Ni6)8B3-Y]97-Nb3 has the biggest Tg, Tx and Trg which are 884 K, 972 K and 0.634, respectively.
Keywords:cluster   glue atom   Fe-base BMG
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