| 间规1,2—聚丁二烯合成的实验室研究 |
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| 引用本文： | 陈德铨. 间规1,2—聚丁二烯合成的实验室研究[J]. 石化技术, 1997, 4(1): 36-41,46 |
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| 作者姓名： | 陈德铨 |
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| 作者单位： | 上海石油化工研究院 |
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| 摘 要： | 报道了使用Ｃｏ－Ａｌ－Ｐ－Ｈ２Ｏ催化体系实验室合成间规１，２－取丁二烯的研究结果，详细讨论了催化组分的加料顺序，老化条件及聚合工艺条件对聚合反应的影响，在此基础上得到最佳工艺条件，进行了模试放大，所得聚合物的基本性能与ＪＳＲ ＲＢ８２０相近。
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| 关 键 词： | 聚丁二烯 间规聚合 实验室 |
SYNTHESIS OF SYNDIOTACTIC 1,2-POLYBUTADIENE |
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| STUDIED IN LABORATORY Chen Dequan. SYNTHESIS OF SYNDIOTACTIC 1,2-POLYBUTADIENE[J]. Petrochemical Industry Technology, 1997, 4(1): 36-41,46 |
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| Authors: | STUDIED IN LABORATORY Chen Dequan |
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| Affiliation: | Shanghai Petrochemical Research Institute |
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| Abstract: | The research results on synthesizing syndiotactic 1,2-polybutadiene with Co-Al-P-H 2O Catalyst system is reported, The effect of addition orders and aging conditions of the catalyst components on polymerization reaction is discussed in detail.Polymerization in autoclare was carried out with the optimum process,the basic properties of the resulting polymer is very similar to that of JSR RB 820. |
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| Keywords: | polybutadiene syndiotactic polymerization |
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