Synthesis and catalytic activity of a novel ruthenium(III) complex containing a sugar-based ligand |
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| Affiliation: | 1. Department of Pharmacology and Pharmacotherapy, Faculty of Medicine, University of Pécs, H-7624, Pécs, Szigeti út 12., Hungary;2. János Szentágothai Research Centre, University of Pécs, H-7624, Pécs, Ifjúság útja 20., Hungary;3. Department of Experimental Zoology and Neurobiology, Faculty of Science, University of Pécs, H-7624, Pécs, Ifjúság útja 6., Hungary;4. Department of Ophthalmology, Faculty of Medicine, University of Pécs, H-7624, Pécs, Nyár u. 8., Hungary;5. 2nd Department of Internal Medicine, Faculty of Medicine, University of Pécs, H-7624, Pécs, Pacsirta u. 1., Hungary;6. Department of Laboratory Medicine, Faculty of Medicine, University of Pécs, H-7624, Pécs, Ifjúság útja 13., Hungary;7. "Kiséri" Veterinarian Praxis, H-6600, Szentes, Sáfrán Mihály u. 43., Hungary;8. Gedeon Richter Plc., H-1475, Budapest, X. Gyömrői út 19-21., Hungary;9. MTA-PTE NAP B Chronic Pain Research Group, Hungary;1. Department of Cardiology, Kepler University Hospital Linz, Johannes Kepler University Linz, Austria;2. 3rd Medical Department – Cardiology and Intensive Care Medicine, Wilhelminenhospital Vienna, Austria;3. Clinic of Internal Medicine II – Department of Cardiology, Paracelsus Medical University of Salzburg, Austria;1. Department of Medicine, The Miriam Hospital, Warren Alpert Medical School of Brown University, Providence, Rhode Island;2. Division of Cardiology, University of Kentucky College of Medicine - Bowling Green Campus, Bowling Green, Kentucky;3. Department of Internal Medicine, University of Kentucky College of Medicine - Bowling Green Campus, Bowling Green, Kentucky;4. Division of Cardiology, CHI St. Vincent Heart Clinic Arkansas, Searcy, Arkansas;5. Division of Cardiology, University of Missouri School of Medicine, Columbia, Missouri;6. Division of Cardiology, Lifespan Cardiovascular Institute, Warren Alpert Medical School of Brown University, Providence, Rhode Island;7. Heart & Vascular Services, Henry Ford Health, Detroit, Michigan |
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| Abstract: | The novel mixed-ligand complex [RuIII(TDL)(bipy)(H2O)]+ (1) (TDL = N-3,5-ditertiarybutylsalicylidine-d-glucosamine; bipy = 2,2′-bipyridine) has been synthesized and characterized. Complex 1 found to catalyze the epoxidation of styrene and oxidize 1-indanol to 1-indanone in dichloromethane using t-BuOOH as a terminal oxidant. Enanantiomeric induction was observed in case of styrene epoxidation. Formation of a high valent Ru(V)-oxo species is proposed to be the catalytic oxidative species. |
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