Nickel‐ or Iron‐Catalyzed Cross‐Coupling of Aryl Carbamates with Arylsilanes

Aryl carbamates were for the first time applied as electrophiles in the cross‐coupling with arylsilanes via nickel or iron catalysis to construct valuable biaryl compounds. This new coupling reaction features a good group tolerance and non‐sensitivity to steric hindrance on both aryl carbamates and arylsilanes.