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Synthesis of nanostructured zirconia electrodeposited films on AISI 316L stainless steel and its behaviour in corrosion resistance assessment
Affiliation:1. Materials Innovation Institute (M2i), Mekelweg 2, 2628 CD Delft, The Netherlands;2. Delft University of Technology, Department of Materials Science and Engineering, Mekelweg 2, 2628 CD Delft, The Netherlands;3. Vrije Universiteit Brussel, Research Group Electrochemical and Surface Engineering, Pleinlaan 2, B-1050 Brussels, Belgium;4. Henkel AG & Co. KGaA, Henkelstr. 67, 40589 Düsseldorf, Germany
Abstract:This work deals with the study of AISI 316L stainless steel samples coated with nanostructured zirconia thin films, using electrodeposition methods. The chemical composition and compounds formed were determined by X-ray photoelectron spectroscopy (XPS). The morphology of zirconia films was analysed by scanning electron microscopy (SEM) and atomic force microscopy (AFM).Corrosion resistance of the coated steel was tested in a chloride environment. XPS analysis results show zirconium element on the metal surface, bound to oxygen-forming zirconia. The anodic polarization curves obtained in Hank's solution show that zirconia coating can be used as protective coating against pitting corrosion of AISI 316L stainless steels.
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