| 重芳烃轻质化催化剂n（Ni）/n（Ni+Mo）的优化与分析 |
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| 引用本文： | 刘航,臧甲忠,范景新,郭春垒,靳凤英,赵训志.重芳烃轻质化催化剂n（Ni）/n（Ni+Mo）的优化与分析[J].无机盐工业,2021,53(12):140-145. |
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| 作者姓名： | 刘航 臧甲忠 范景新 郭春垒 靳凤英 赵训志 |
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| 作者单位： | 1.中海油天津化工研究设计院有限公司,天津3001312.天津市炼化催化技术工程中心 |
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| 基金项目： | 中国海洋石油集团公司项目(CNOOC-KJ 135FZDXM 00 LH 009 ZS-2016) |
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| 摘 要： | 以β分子筛为载体,在保持金属总负载量不变的情况下,采用等体积浸渍法制备了4种不同n（Ni）/n（Ni+Mo）的催化剂。分别采用X射线衍射（XRD）、比表面积测试（BET）、氨程序升温脱附（NH3-TPD）、氢程序升温还原（H2-TPR）、氢程序升温脱附（H2-TPD）和热重-差热分析（TG-DTG）等方法对催化剂进行了表征。结果表明,4种催化剂的酸量和酸强度相近,在n（Ni）/n（Ni+Mo）等于基准+0.2时,Mo与载体之间的相互作用最弱,其氢气吸附量最多且积炭量最少;采用某炼厂重整C10+ 重芳烃对4种催化剂进行评价,结果表明n（Ni）/n（Ni+Mo）等于基准+0.2催化剂具有最优的催化活性和稳定性。上述结果表明,影响重芳烃轻质化催化剂活性和稳定性的关键因素是催化剂氢气吸附量的多少,氢气吸附量越多金属表面的溢流氢效应越明显,积炭前驱体被溢流氢及时消除,从而保护了催化剂的加氢活性中心不被积炭覆盖,有助于催化剂在较高活性下保持稳定。
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| 关 键 词： | 重芳烃轻质化 催化剂 加氢 n（Ni）/n（Ni+Mo） |
| 收稿时间： | 2021-03-09 |
Optimization and analysis of n（Ni）/n（Ni+Mo） of heavy aromatics to light aromatics catalyst |
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| LIU Hang,ZANG Jiazhong,FAN Jingxin,GUO Chunlei,JIN Fengying,ZHAO Xunzhi.Optimization and analysis of n（Ni）/n（Ni+Mo） of heavy aromatics to light aromatics catalyst[J].Inorganic Chemicals Industry,2021,53(12):140-145. |
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| Authors: | LIU Hang ZANG Jiazhong FAN Jingxin GUO Chunlei JIN Fengying ZHAO Xunzhi |
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| Affiliation: | 1. CenerTech Tianjin Chemical Research and Design Institute Co. Ltd.,CNOOC,Tianjin 300131,China2. Tianjin Refinery Catalytic Technology Engineering Center |
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| Abstract: | In order to further improve the activity and stability of heavy aromatic light catalyst,four catalysts with different n（Ni）/n（Ni+Mo） atomic ratios were prepared by incipient-wetness impregnation method with zeolite β as support.The total mass of the metal was same.The catalysts were characterized by XRD,NH3-TPD,H2-TPR,H2-TPD and TG-DTG.The results showed that the acid content and acid strength of the four catalysts were similar,and when the n（Ni）/n（Ni+Mo） atomic ratio was of standard+0.2,the interaction between Mo and the support was the weakest,with the maximum adsorption capacity of H2 and the minimum carbon deposition.Four catalysts were evaluated by using reforming C10+ heavy aromatics.The results showed that the catalyst with the n（Ni）/n（Ni+Mo） atomic ratio of standard+0.2 had the optimal catalytic activity and stabi-lity.The above results showed that the key factor affecting the activity and stability of catalyst was the amount of H2 adsorption,the more H2 was adsorbed,the more obvious the hydrogen overflow effect was on metal surface.The precursor of carbon deposition was eliminated in time by overflow hydrogen,thus,the hydrogenation active center of the catalyst was protected from carbon deposition,it was helpful to keep the catalyst stable at high activity. |
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| Keywords: | heavy aromatics to light aromatics catalyst hydrogenation n（Ni）/n（Ni+Mo） atomic ratios |
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