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沈阳冶炼厂的炼铜烟尘含有多种有价金属及有害成分砷,为消除烟害和综合回收有价金属,试验研究了“密闭浸取”新方案,可使烟尘中的锌、铟、镉、砷大部分浸入溶液中,而铜、铅、铋则留在浸渣里,达到了粗分离的效果。本研究是进一步对此密闭浸取渣探索用浮选回收铜和湿法提铋的选冶联合处理方法,分别得出铜精礦、铅精礦和海绵粗铋三种产品,以达到综合回收利用的目的。试验结果表明,铜烟尘密闭酸浸渣用黑药作捕收剂在弱酸性(pH5-6)矿浆中浮选,以水玻璃作细泥分散剂,碳酸钠作pH调整剂,并添加少量硫化钠作活化剂,采用分段加药、分段浮选、一次精选的工艺流程,可获得含铜7.33%的精礦,铜回收率为84.8%。浮选铜后的铅铋渣用加食盐硫酸常压浸取法,可将97%铋浸出,而铅的浸出<2%。此浸取液用铁粉置换,得出海绵粗铋,铋置换率99%左右。此浸取渣为含铅57%的铅精礦,可作为炼铅的原料。 相似文献
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介绍了用空气氧化低价铁,再分别用石灰和碳酸钠中和沉淀锌冶炼过程产生的酸性废水中铁和锌的工艺,研究了溶液pH值、空气流速、沉淀剂种类及反应时间对铁去除率、锌损失率及沉锌率的影响。研究结果表明,氧化沉淀除铁的最佳反应条件为pH值3.5,空气通入流速20 mL/min,反应时间4 h,此时铁去除率为99.54%,锌损失率为2.50%;沉淀提锌较适宜的沉淀剂为碳酸钠,最佳反应条件为pH值7.5,反应时间30 min,此时沉锌率为99.60%,干燥后沉淀中锌质量分数为52.03%,折合碳酸锌的质量分数高达99.77%。 相似文献
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针对氰化提金工艺酸浸渣中低品位金属铅的综合回收,采用盐浸法对金属铅进行了浸出实验研究,通过正交试验详细考察了浸出液固质量比、浸出温度、氯化钠浓度、浸出pH和浸出时间等因素对浸铅率的影响。结果表明,浸出液固质量比为5、浸出温度为333.15 K、氯化钠质量分数为30%、pH=0、浸出时间为4 h的实验条件下,最佳平均浸铅率为92.05%,相对标准偏差RSD=4.3‰;室温下最佳平均浸铅率为90.20%,RSD=4.1‰。因此,酸浸渣常温盐浸提铅是综合利用矿产资源回收铅及提高金、银回收率的有效途径。 相似文献
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采用NaOH溶液浸泡法分离废旧磷酸铁锂电池的铝箔和正极材料,采用有机溶剂浸泡法分离正极活性物质和粘结剂,采用酸浸-沉淀法回收废旧磷酸铁锂电池中的铁和锂,考察了回收废旧磷酸铁锂电池中的铁和锂,考察了试剂浓度、固液比和反应时间等因素对处理效果的影响,实验结果表明:在NaOH溶液的浓度为0.4 mol/L,NaOH溶液与正极片的液固比(m L/g)为10的条件下,将正极废片在NaOH溶液中浸泡10 min,可以实现铝箔与正极材料的完全分离;在温度为60℃,有机溶剂与正极材料的液固比(m L/g)为10的条件下,将正极材料在有机溶剂NMP中浸泡30 min,可以实现正极活性物质与粘结剂的完全分离;在硫酸浓度为4 mol/L,液固比(m L/g)为10,反应温度为60℃的条件下,将正极活性物质在硫酸-双氧水体系中反应2 h,铁和锂的浸出率分别达到96.4%和97.0%;在浸出液的pH为3时,铁的沉淀率达到99.0%;在除去铁的浸出液中,碳酸钠的用量为200 g/L时,锂的沉淀率达到98.9%。 相似文献
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钒铅锌矿含有多种有价金属,V品位高,具有较高的经济价值。本工作采用硫酸浸出法从该矿中提取钒锌,对浸出过程热力学进行分析,通过条件实验研究硫酸浓度、液固比、浸出时间、搅拌速率、浸出温度等条件对钒、铅、锌等主要有价金属浸出率的影响。结果表明,在较高pH值及较高温度下,浸出液中V会出现水解,含V的水解产物留在浸出渣中影响V浸出率。得到最优浸出条件为:硫酸浓度200 g/L,液固比3:1,浸出时间30 min,搅拌速率200 r/min,浸出温度为30℃。最优条件下V浸出率可达97.90%,Zn浸出率为97.11%,Fe浸出率<1%,Pb浸出率<0.01%。动力学分析结果表明,浸出过程的反应速率受扩散过程控制。酸浸过程使V和Zn进入浸出液,Pb和Fe留在浸出渣中,所得浸出液可使用离子交换或萃取法分离V和Zn。浸出渣中含钒0.41wt%、锌0.61wt%、铁15.50wt%、铅47.70wt%,主要成分为PbSO4和FeO(OH),可返回火法炼铅系统。 相似文献
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Studies were carried out for selective leaching of Cu with simultaneous avoidance of iron dissolution during leaching of oxidized copper ore in an aqueous NH3-(NH4)2SO4 system. The effects of leaching parameters, such as ammonia concentration, ammonium sulphate concentration, leaching time, and solid-to-liquid ratio, were investigated on leaching of copper. A 2n factorial experimental design method in the dissolution experiments was used. In addition, the “Steepest Ascent” method was also applied to determine the optimum leaching conditions. It was observed that the most effective parameters on the leaching of copper were ammonia concentration and leaching time. Only 0.17% of iron in ore was dissolved in ammonia and ammonium sulphate medium. The optimum conditions established for maximum copper recovery were: ammonia concentration 2.824 mol L-1, ammonium sulphate concentration 0.236 mol L-1, solid-to-liquid ratio 0.167 g mL-1, leaching time 2 h. Fixed parameters chosen in the experiments were: room temperature, average particle size 2.8 mm, stirring speed 500 rpm. Under the optimum conditions established for maximum copper recovery, the percentage of leached copper was 98.87. 相似文献
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研究了利用微生物球菌从低品位含锗褐煤中浸出锗的新方法,探讨了球菌从低品位含锗褐煤中浸出锗的主要影响因素,获得了从低品位含锗褐煤中浸出锗的适宜条件:煤浆质量分数为10%,浸出剂球菌浓度为109个/mL,浸出温度为30℃,浸出时间为8d,浸出液的pH值为4.0,褐煤的平均粒度为0.20mm ̄1.00mm,接种量的影响是不显著的。褐煤中锗的浸出率可达84%以上,和H2SO4浸出相比,锗的浸出率可提高20%左右,浸出时间至少缩短8d,节约H2SO4 90%左右。 相似文献
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Turan Çalban Sabri Çolak Murat Yeşilyurt 《Chemical Engineering Communications》2013,200(11):1515-1524
Studies were carried out for selective leaching of Cu with simultaneous avoidance of iron dissolution during leaching of oxidized copper ore in an aqueous NH3-(NH4)2SO4 system. The effects of leaching parameters, such as ammonia concentration, ammonium sulphate concentration, leaching time, and solid-to-liquid ratio, were investigated on leaching of copper. A 2n factorial experimental design method in the dissolution experiments was used. In addition, the “Steepest Ascent” method was also applied to determine the optimum leaching conditions. It was observed that the most effective parameters on the leaching of copper were ammonia concentration and leaching time. Only 0.17% of iron in ore was dissolved in ammonia and ammonium sulphate medium. The optimum conditions established for maximum copper recovery were: ammonia concentration 2.824 mol L?1, ammonium sulphate concentration 0.236 mol L?1, solid-to-liquid ratio 0.167 g mL?1, leaching time 2 h. Fixed parameters chosen in the experiments were: room temperature, average particle size 2.8 mm, stirring speed 500 rpm. Under the optimum conditions established for maximum copper recovery, the percentage of leached copper was 98.87. 相似文献
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不锈钢酸洗污泥含有高浓度的Fe、Cr、Ni金属离子,属于危险固体废弃物。本文对不锈钢酸洗污泥浸出液有价组分梯级分离展开研究,探讨了磷酸钠用量、浸出液初始pH、反应温度、搅拌时间对酸洗污泥中浸出液中Fe、Cr、Ni分离效果的影响。确定Cr3+沉淀的最佳工艺条件:P/Cr摩尔比为1.00,初始pH为1.00,反应温度为90℃,反应时间70min。Cr3+平均沉淀率为94.47%,Fe2+、Ni2+平均沉淀率为0.88%、0.78%。Fe3+优化条件为P/Fe体积比0.80、初始pH为1.00、反应温度为45℃、搅拌时间为60min,Fe3+沉淀率最高为99.83%、Ni2+沉淀率稳定在0.68%,证明了磷酸盐沉淀法可以有效分离不锈钢酸洗污泥浸出液中Fe、Cr、Ni,为不锈钢酸洗污泥铁、镍、铬分离提供理论依据和技术应用参考。 相似文献