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微波化学法原油破乳脱水工艺的优化 总被引:1,自引:0,他引:1
对原油乳状液分别采用热化学法及微波热化学法进行了破乳脱水实验。对于本实验所用含水量为78%的1#原油乳状液,采用热化学方法时,破乳剂的用量为100 mg/L,加热温度为65℃,加热9 min后,可脱水约为96.2%;而采用微波化学法时,破乳剂的用量为50 mg/L,辐射时间为10 s,沉降时间为2 min,可脱水约为94.9%。提出了原油乳状液脱水的工艺为对原油乳状液采用二次脱水处理,首先采用微波化学法,再对一次脱水后的上层原油乳状液采用加热法。对1#原油乳状液,一次微波辐射脱水后,上层油的含水量在18%左右;对上层油进行加热二次脱水后,原油的含水率小于0.3%,可得到合格原油。 相似文献
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正交设计在微波辐射原油脱水中的应用研究 总被引:3,自引:2,他引:1
研究了微波辐射对原油乳状液脱水的机理及其3个主要影响因素,用正交实验设计法考察微波辐射对原油乳状液脱水的最佳实验条件,以达到较好的脱水效果。采用MSP-100D微波消解系统对水质量分数为50%的大庆原油乳化液进行微波辐射实验。通过极差和方差分析可知,在影响大庆原油乳化液脱水率的3个因素中系统压力值影响最大,微波辐射功率其次,微波辐照时间影响最小。在微波辐射功率为400W,辐照时间为10min,系统压力值为0.3MPa,水质量分数为50%的大庆原油乳化液的平均脱水率高迭93.9896。实验结果表明.微波辐射原油脱水具有效率高,时间短,无污染和节约能源等优点,有良好的工业化应用前景。 相似文献
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《中国石油和化工标准与质量》2017,(4)
对原油乳状液进行破乳脱水是石油生产和加工过程中一个重要的步骤,目前由于石油的不断开发和各种新型采油技术被应用于石油的开采之中,导致了原油乳状液的稳定性越来越强,原油破乳脱水工作面临的困难也越来越大,因此需要研究人员通过不断的研究探索,开发出更适合生产需要的破乳剂,促进石油的生产和加工工业的发展。本文从原油破乳剂的破乳机理出发,介绍了原油破乳剂的研究现状,并对其发展方向进行了探讨。 相似文献
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石油开采、集输、加工过程中会面临复杂的工况条件,原油中的天然表面活性剂与人工添加乳化剂以及纳微米固体颗粒共同形成石油Pickering乳液,使得油水体系呈稳定的水包油(O/W)、油包水(W/O)或多重乳化状态。油水乳状液作为注水采油的主要产物,其高效破乳是石油工业链条中的普遍需求。目前对于石油Pickering的破乳仍然借鉴普通油水乳液的方法,而对于成因复杂的油水乳状液,以去除成膜乳化剂为目标的氧化破乳法比传统破乳法的效果更佳。为此,本文基于高效的氧化破乳机制,介绍了石油Pickering乳液的特点及危害,与非氧化反应类型的传统化学破乳法进行对比,综述了分子氧化、光催化氧化、电化学氧化三类技术对于不同来源及特征的油水乳状液的破乳进展。通过对每种方法的机理过程、应用实例、优缺点等方面详细分析,总结了分子氧化、光催化氧化、电化学氧化在石油Pickering乳液破乳中的局限性,并对今后如何实现石油Pickering乳液精准破乳提出展望。 相似文献
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反相乳液聚合研究进展 总被引:6,自引:0,他引:6
刘玉勇 《化学推进剂与高分子材料》2003,1(6):27-30
反相乳液聚合与溶液聚合相比具有聚合速率高等优点 ,广泛应用于制备聚苯胺、增稠剂 ,以及造纸、石油开采等行业。着重介绍反相乳液聚合的胶束成核和液滴均相成核机理 ,阐述其动力学方程和数学模型。还介绍了反相乳液聚合的应用 相似文献
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Onkar N. Anand Kalyan D. Neemla Ved P. Malik 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1979,29(8):506-514
The average molecular weight distribution, emulsion stability of oil—water emulsion, the chemical structure of the hydrocarbon portions of petroleum sulphonates, and surface active properties have been determined with a view to establishing a correlation between the chemical structure of petroleum sulphonates and their emulsion stability characteristics. It has been found that the emulsion stability of oil—water emulsions imparted by sodium petroleum sulphonates depends on: (i) average molecular weight of sodium petroleum sulphonates; (ii) their molecular weight distribution; (iii) oil—water interfacial tension; (iv) hydrophile—lipophile balance values. The structural parameters which predominantly effect the emulsion stability are the ratio of the percentage distribution of carbon atoms in paraffin side chains to the percentage distribution of carbon atoms, the aromatic rings (CP/CA), the relative proportions of long chain mono-aromatics and the orientation of the sulphonate group relative to the paraffin alkyl chains in the molecules. 相似文献
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油气田的开发建设一直是我国石油行业中的重中之重。随着我国石油行业的快速发展,各项领域对石油与天然气的需求也越来越大。但是,随着石油与天然气的大力开采,对环境产生了不良的影响。对此,通过对油气田的开发、油气田开发建设对环境的影响以及环境的保护对策等方面进行了简略的说明,希望对我国以后油气田开发建设有一定的指导作用。 相似文献
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The influence of petroleum sulphonate (TRS) on interfacial properties and stability of the emulsions formed by formation water and asphaltene, resin and crude model oils from Gudong crude oil was investigated by measurement of interfacial shear viscosity, interfacial tension (IFT) and emulsion stability. With increasing petroleum sulphonate concentration, IFT between the formation water and the asphaltene, resin and crude model oils decreases significantly. The interfacial shear viscosity and emulsion stability of asphaltene and crude model oil system increase for the petroleum sulphonate concentration in the range 0.1% to 0.3%, and decrease slightly when the concentration of the surfactant is 0.5%. There exists a close correlation between the interfacial shear viscosity and the stability of the emulsions formed by asphaltene or crude model oils and petroleum sulphonate solution. The stability of the emulsions is determined by the strength of the interfacial film formed of petroleum sulphonate molecules and the natural interfacial active components in the asphaltene fraction and the crude oil. The asphaltene in the crude oil plays a major role in determining the interfacial properties and the stability of the emulsions. 相似文献
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《分离科学与技术》2012,47(7):1884-1895
Abstract Droplet size is a key factor in the treatment of oil‐in‐water (O/W) emulsions, because of its influence on emulsion properties. The addition of a coagulant salt generally causes emulsion destabilization, increasing the droplet size, and enhancing coalescence between oil droplets, which helps its further treatment. The influence of CaCl2 addition on droplet size distribution of a commercial O/W emulsion used in machining processes was studied in order to facilitate oil removal and to improve its further treatment by centrifugation, ultrafiltration (UF) and vacuum evaporation. The critical coagulation concentration (CCC) was observed at a CaCl2 concentration of 0.05 M. The quality of the final aqueous effluent, expressed as its chemical oxygen demand (COD) value, was compared for all treatments. The highest COD values were obtained for centrifugation, while the COD of the UF permeate was approximately constant for all UF trials. The best effluent quality was obtained by vacuum evaporation. A combination of these techniques should be appropriate for most industrial treatments of O/W emulsions, depending on the subsequent use of the resulting aqueous effluent. 相似文献
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石油醚W/O乳状液及其液膜稳定性 总被引:17,自引:0,他引:17
以破乳率为衡量标准,借助显微镜直接观察,探讨了乳状液含水量、表面活性剂用量、乳化时间、乳化强度等因素对石油醚W/O型乳状液体系稳定性的影响。在实验范围内,乳状液含水量的提高及表面活性剂用量的增加,有利于乳状液的稳定;存在较优的乳化时间20min和乳化强度4000rmin-1。选取脂肪烃、芳香烃、混合烃共6种不同油相制备乳状液,对比其稳定性的差异。此外,还初步考察了石油醚W/O/W液膜溶胀和泄漏问题,结果表明该乳状液膜泄漏率低于3.5%,表观溶胀率约为20%。 相似文献
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Crude oil blending is a very common practice in petroleum refineries, where the main focus is to minimize the total purchase cost of crude oils under specified blending oil properties. Crude oil blending actually has significant impacts on energy consumption from heating furnaces during crude oil processing. Conceivably, furnace energy consumption from burning fuels such as natural gas, fuel oil, or propane causes huge amounts of CO2 emissions. In this paper, a methodology framework for crude oil blending and processing with simultaneous consideration of energy, emission, and economic profit (E3) is developed. It includes four stages of work: steady‐state modeling, heating energy consumption calculation, emission model development, and economic evaluation. With Aspen HYSYS simulation, the developed methodology provides a quantitative support for refinery to identify an optimal E3 operating strategy. A case study is implemented to demonstrate the efficacy of this methodology. 相似文献