Energy,exergy, and sustainability a novel comparison of conventional gas turbine with fuel cell integrated hybrid power cycle

In this paper, six novel modified exergy relations are explored to determine the precise estimation of exergy destruction and to identify which component has the most improvement potential. For this, three power generation cycles are considered, i.e., simple gas turbine (SGT), recuperated gas turbine (RGT), are compared with a novel hybrid system (SOFC-RGT: Solid Oxide Fuel Cell-RGT), which operates with fuel flexibility as well as enhanced work-output and thermal efficiency. For energy, exergy, and sustainability studies, numerical modeling is conducted using MATLAB. At r_p = 4, TIT = 1250 K, an exclusive comparison has been made between proposed configurations based on thermodynamic modeling and exergy-based sustainability index. It is found that with the inclusion of a recuperator and a fuel cell in the proposed cycles, the thermal and sustainability performance tend to increase significantly. Whereas, exergy destruction increases but has minimal impact on comparing thermal performance and sustainability index. In terms of sustainability, RGT is 30.76% more sustainable than SGT, while SOFC-GT is 63.39% more sustainable than RGT.     

应用甲烷自热重整技术的燃气轮机循环火用分析

提出了一种应用甲烷重整技术的燃气轮机新循环。首先,根据系统的工作过程,应用热力学平衡方法分析燃烧室反应的热平衡;其次依据热力学第二定律,研究了燃气轮机新循环火用效率的变化趋势。结果显示:新循环燃烧消耗的甲烷量小于供给量,与CO2和H2O重整消耗的甲烷量的变化趋势与反应平衡常数的大小有关。在相同燃料量的条件下,与简单循环相比,新循环的火用效率得到大幅提高,涨幅为5.05%-15.57%。     

Energy and exergy analyses of an integrated SOFC and coal gasification system

This paper examines an integrated gasification and solid oxide fuel cell (SOFC) system with a gas turbine and steam cycle that uses heat recovery of the gas turbine exhaust. Energy and exergy analyses are performed with two different types of coal. For the two different cases, the energy efficiency of the overall system is 38.1% and 36.7%, while the exergy efficiency is 27% and 23.2%, respectively. The effects of changing the reference temperature on the exergy destruction and exergy efficiency of different components are also reported. A parametric study on the effects of changing the pressure ratio on the component performance is presented.     

Thermodynamic analysis of an integrated power generation system driven by solid oxide fuel cell

A new integrated power generation system driven by the solid oxide fuel cell (SOFC) is proposed to improve the conversion efficiency of conventional energy by using a Kalina cycle to recover the waste heat of exhaust from the SOFC-GT. The system using methane as main fuel consists an internal reforming SOFC, an after-burner, a gas turbine, preheaters, compressors and a Kalina cycle. The proposed system is simulated based on the developed mathematical models, and the overall system performance has been evaluated by the first and second law of thermodynamics. Exergy analysis is conducted to indicate the thermodynamic losses in each components. A parametric analysis is also carried out to examine the effects of some key thermodynamic parameters on the system performance. Results indicate that as compressor pressure ratio increases, SOFC electrical efficiency increases and there is an optimal compressor pressure ratio to reach the maximum overall electrical efficiency and exergy efficiency. It is also found that SOFC electrical efficiency, overall electrical efficiency and exergy efficiency can be improved by increasing air flow rate. Also, the largest exergy destruction occurs in the SOFC followed by the after-burner, the waste heat boiler, the gas turbine. The compressor pressure ratio and air flow rate have significant effects on the exergy destruction in some main components of system.     

Thermodynamic,exergoeconomic and exergoenvironmental analyses and optimization of a solid oxide fuel cell-based trigeneration system

This study proposes a trigeneration system based on solid oxide fuel cell (SOFC) for generating power, cooling and heating simultaneously. The system mainly contains a SOFC, a gas turbine (GT), an organic Rankine cycle (ORC), a steam ejector refrigerator (SER) and a heat exchanger. The thermodynamic, exergoeconomic and exergoenvironmental models of proposed trigeneration system are developed, and the effects of design parameters on system performances are analyzed. The results indicate that the system average product cost and environmental impact per unit of exergy increase with SOFC inlet temperature and working pressure, the pinch point temperature difference and evaporating pressure of Generator, while decrease with the current density of fuel cell. Finally, optimization is performed to achieve the optimal exergy-based performance. It is revealed that though the system exergy efficiency is decreased by 7.64% after optimization, the system average product cost and environmental impact per unit of exergy are significantly reduced.     

Thermoeconomic analysis of SOFC-GT-VARS-ORC combined power and cooling system

The integration of the gas turbine cycle and organic Rankine cycle with the solid oxide fuel cell for power generation is quite prevalent. However, the need is also felt for systems capable of providing power with cooling. Therefore, it is proposed to integrate solid oxide fuel cell with gas turbine cycle, vapour absorption refrigeration system and organic Rankine cycle through the heat available with fluid in the cycle. Here intercooled and reheat gas turbine cycle is integrated with solid oxide fuel cell. Heat rejected in intercooling is used in vapour absorption refrigeration system for cooling. This paper presents thermoeconomic analysis. Results show that the combination of solid oxide fuel cell-gas turbine-vapour absorption refrigeration system-organic Rankine cycle yields increase in efficiency to 68.79% as compared to 58.88% from combined solid oxide fuel cell-gas turbine cycle. The cost of electricity per unit power output is found as 1939.93 $/kW.     

Energy,exergy and exergo-environmental impact assessment of a solid oxide fuel cell coupled with absorption chiller & cascaded closed loop ORC for multi-generation

A novel solid oxide fuel cell (SOFC) multigeneration system fueled by biogas derived from agricultural waste (maize silage) is designed and analyzed from the view point of energy and exergy analysis. The system is proposed in order to limit the greenhouse gas emissions as it uses a renewable energy source as a fuel. Electricity, domestic hot water, hydrogen and cooling load are produced simultaneously by the system. The system includes a solid oxide fuel cell; which is the primary mover, a biogas digester subsystem, a cascaded closed loop organic Rankine cycle, a single effect LiBr-water absorption refrigeration cycle, and a proton exchange membrane electrolyzer subsystem. The proposed cascaded closed-loop ORC cycle is considered as one of the advanced heat recovery technologies that significantly improve thermal efficiency of integrated systems. The thermal performance of the proposed system is observed to be higher in comparison to the simple ORC and the recuperated ORC cycles. The integration of a splitter to govern the flue gas separation ratio is also introduced in this study to cater for particular needs/demands. The separation ratio can be used to vary the cooling load or the additional power supplied by the ORC to the system. It is deduced that net electrical power, cooling load, heating capacity of the domestic hot water and total energy and exergy efficiency are 789.7 kW, 317.3 kW, 65.75 kW, 69.86% and 47.4% respectively under integral design conditions. Using a parametric approach, the effects of main parameters on the output of the device are analyzed. Current density is an important parameter for system performance. Increasing the current density leads to increased power produced by the system, decreased exergy efficiency in the system and increased energy efficiency. After-burner, air and fuel heat exchangers are observed to have the highest exergy destruction rates. Lower current density values are desirable for better exergy-based sustainability from the exergetic environmental impact assessment. Higher current density values have negative effect on the environment.     

Design and partial load exergy analysis of hybrid SOFC–GT power plant

This paper presents a full and partial load exergy analysis of a hybrid SOFC–GT power plant. The plant basically consists of: an air compressor, a fuel compressor, several heat exchangers, a radial gas turbine, mixers, a catalytic burner, an internal reforming tubular solid oxide fuel cell stack, bypass valves, an electrical generator and an inverter. The model is accurately described. Special attention is paid at the calculation of SOFC overpotentials. Maps are introduced, and properly scaled, in order to evaluate the partial load performance of turbomachineries. The plant is simulated at full-load and part-load operation, showing energy and exergy flows trough all its components and thermodynamic properties at each key-point. At full-load operation a maximum value of 65.4% of electrical efficiency is achieved. Three different part-load strategies are introduced. The off-design operation is achieved handling the following parameters: air mass flow rate, fuel mass flow rate, combustor bypass, gas turbine bypass, avoiding the use of a variable speed control system. Results showed that the most efficient part-load strategy corresponded to a constant value of the fuel to air ratio. On the other hand, a lower value of net electrical power (34% of nominal load) could be achieved reducing fuel flow rate, at constant air flow rate. This strategy produces an electrical efficiency drop that becomes 45%.     

Thermodynamic performance assessment of an indirect intercooled reheat regenerative gas turbine cycle with inlet air cooling and evaporative aftercooling of the compressor discharge

This study provides a computational analysis to investigate the effects of cycle pressure ratio, turbine inlet temperature (TIT), and ambient relative humidity (φ) on the thermodynamic performance of an indirect intercooled reheat regenerative gas turbine cycle with indirect evaporative cooling of the inlet air and evaporative aftercooling of the compressor discharge. Combined first and second‐law analysis indicates that the exergy destruction in various components of gas turbine cycles is significantly affected by compressor pressure ratio and turbine inlet temperature, and is not at all affected by ambient relative humidity. It also indicates that the maximum exergy is destroyed in the combustion chamber; which represents over 60% of the total exergy destruction in the overall system. The net work output, first‐law efficiency, and the second‐law efficiency of the cycle significantly varies with the change in the pressure ratio, turbine inlet temperature and ambient relative humidity. Results clearly shows that performance evaluation based on first‐law analysis alone is not adequate, and hence more meaningful evaluation must include second‐law analysis. Decision makers should find the methodology contained in this paper useful in the comparison and selection of gas turbine systems. Copyright © 2006 John Wiley & Sons, Ltd.     

Thermodynamic analysis and assessment of an integrated hydrogen fuel cell system for ships

In this thermodynamic investigation, an integrated energy system based on hydrogen fuel is developed and studied energetically and exergetically. The liquefied hydrogen fueled solid oxide fuel cell (SOFC) based system is then integrated with a steam producing cycle to supply electricity and potable water to ships. The first heat recovery system, after the fuel cells provide thrust for the ship, is by means of a turbine while the second heat recovery system drives the ship's refrigeration cycle. This study includes energy and exergy performance evaluations of SOFC, refrigeration cycle and ship thrust engine systems. Furthermore, the effectiveness of SOFCs and a hydrogen fueled engine in reducing greenhouse gas emissions are assessed parametrically through a case study. The main propulsion, power generation from the solid oxide fuel cells, absorption chiller, and steam bottoming cycle systems together have the overall energy and exergy efficiencies of 41.53% and 37.13%, respectively.     

Thermo-economic modeling of a solid oxide fuel cell/gas turbine power plant with semi-direct coupling and anode recycling

Power generation using gas turbine (GT) power plants operating on the Brayton cycle suffers from low efficiencies, resulting in poor fuel to power conversion. A solid oxide fuel cell (SOFC) is proposed for integration into a 10 MW gas turbine power plant, operating at 30% efficiency in order to improve system efficiencies and economics. The SOFC system is semi-directly coupled to the gas turbine power plant, with careful attention paid to minimize the disruption to the GT operation. A thermo-economic model is developed for the hybrid power plant, and predicts an optimized power output of 21.6 MW at 49.2% efficiency. The model also predicts a breakeven per-unit energy cost of USD 4.70 ¢/kWh for the hybrid system based on futuristic mass generation SOFC costs. Results show that SOFCs can be semi-directly integrated into existing GT power systems to improve their thermodynamic and economic performance.     

中冷再热STIG循环的火用分析

对中冷再热注蒸汽燃气轮机（ＳＴＩＧ）循环火用分析结果表明：中冷再热ＳＴＩＧ循环比简单ＳＴＩＧ循环的火用效率显著提高。同时,分析了设备性能和各循环参数对火用效率的影响,分析了各种不可逆损失产生的部位,得出了与热平衡本质不同的结论     

Exergy analysis of a cogeneration plant using coal gasification and solid oxide fuel cell

This paper presents exergy analysis of a conceptualized combined cogeneration plant that employs pressurized oxygen blown coal gasifier and high‐temperature, high‐pressure solid oxide fuel cell (SOFC) in the topping cycle and a bottoming steam cogeneration cycle. Useful heat is supplied by the pass‐out steam from the steam turbine and also by the steam raised separately in an evaporator placed in the heat recovery steam generator (HRSG). Exergy analysis shows that major part of plant exergy destruction takes place in gasifier and SOFC while considerable losses are also attributed to gas cooler, combustion chamber and HRSG. Exergy losses are found to decrease with increasing pressure ratio across the gas turbine for all of these components except the gas cooler. The fuel cell operating temperature influences the performance of the equipment placed downstream of SOFC. Copyright © 2005 John Wiley & Sons, Ltd.     

Performance assessment and optimization of an integrated solid oxide fuel cell-gas turbine cogeneration system

The combined solid oxide fuel cells and gas turbine (SOFC/GT) system is known to be a potential alternative for distributed power generation. In this paper, a novel SOFC/GT based cogeneration system, which integrated a transcritical carbon dioxide cycle (TRCC) with a LNG cold energy utilization system is proposed. A mathematical (zero-dimensional) model is developed to analyze the co-generation system performance from the perspective of thermodynamic (energy and exergy) and economic costs. The main parameters of the system are chosen to analyze their effects on thermodynamic performance. The results show that the current system can achieve 64.40% thermal efficiency and 62.13% exergy efficiency under given conditions, and can further improve efficiency through parameter optimization. Finally, the multi-objective optimization program using NSGA-II (Non-dominated Sorting Genetic Algorithm II) is used to obtain the optimal value of the system design parameters. In the multi-objective analysis, the thermodynamic efficiency and economic cost of the system are considered as objective functions. The optimization results show that the final optimized design selected from the Pareto front can achieve 63.08% thermal efficiency and 61.10% exergy efficiency, respectively.     

Novel and optimal integration of SOFC-ICGT hybrid cycle: Energy analysis and entropy generation minimization

Integrating fuel cells with conventional gas turbine based power plant yields higher efficiency, especially solid oxide fuel cell (SOFC) with gas turbine (GT). SOFCs are energy efficient devices, performance of which are not limited to Carnot efficiency and considered as most promising candidate for thermal integration with Brayton cycle. In this paper, a novel and optimal thermal integration of SOFC with intercooled-recuperated gas turbine has been presented. A thermodynamic model of a proposed hybrid cycle has been detailed along with a novelty of adoption of blade cooled gas turbine model. On the basis of 1st and 2nd law of thermodynamics, parametric analysis has been carried out, in which impact of turbine inlet temperature and compression ratio has been observed on various output parameters such as hybrid efficiency, hybrid plant specific work, mass of blade coolant requirement and entropy generation rate. For optimizing the system performance, entropy minimization has been carried out, for which a constraint based algorithm has been developed. The result shows that entropy generation of a proposed hybrid cycle first increases and then decreases, as the turbine inlet temperature of the cycle increases. Furthermore, a unique performance map has also been plotted for proposed hybrid cycle, which can be utilized by power plant designer. An optimal efficiency of 74.13% can be achieved at TIT of 1800 K and r_p,c 20.     

Thermo-economic modeling of an indirectly coupled solid oxide fuel cell/gas turbine hybrid power plant

Power generation using gas turbine (GT) power plants operating on the Brayton cycle suffers from low efficiencies, resulting in poor fuel to power conversion. A solid oxide fuel cell (SOFC) is proposed for integration into a 10 MW gas turbine power plant, operating at 30% efficiency, in order to improve system efficiencies and economics. The SOFC system is indirectly coupled to the gas turbine power plant, paying careful attention to minimize the disruption to the GT operation. A thermo-economic model is developed for the hybrid power plant, and predicts an optimized power output of 20.6 MW at 49.9% efficiency. The model also predicts a break-even per-unit energy cost of USD 4.65 ¢ kWh⁻¹ for the hybrid system based on futuristic mass generation SOFC costs. This shows that SOFCs may be indirectly integrated into existing GT power systems to improve their thermodynamic and economic performance.     

Performance assessment of a direct steam solar power plant with hydrogen energy storage: An exergoeconomic study

Power generation and its storage using solar energy and hydrogen energy systems is a promising approach to overcome serious challenges associated with fossil fuel-based power plants. In this study, an exergoeconomic model is developed to analyze a direct steam solar tower-hydrogen gas turbine power plant under different operating conditions. An on-grid solar power plant integrated with a hydrogen storage system composed of an electrolyser, hydrogen gas turbine and fuel cell is considered. When solar energy is not available, electrical power is generated by the gas turbine and the fuel cell utilizing the hydrogen produced by the electrolyser. The effects of different working parameters on the cycle performance during charging and discharging processes are investigated using thermodynamic analysis. The results indicate that increasing the solar irradiation by 36%, leads to 13% increase in the exergy efficiency of the cycle. Moreover, the mass flow rate of the heat transfer fluid in solar system has a considerable effect on the exergy cost of output power. Solar tower has the highest exergy destruction and capital investment cost. The highest exergoeconomic factor for the integrated cycle is 60.94%. The steam turbine and PEM electrolyser have the highest share of exergoeconomic factor i.e., 80.4% and 50%, respectively.     

Thermodynamic modeling and exergy investigation of a hydrogen-based integrated system consisting of SOFC and CO2 capture option

The current study deals with the thermodynamic modeling of an innovative integrated plant based on solid oxide fuel cell (SOFC) with liquefied natural gas (LNG) cold energy supply. For the suggested innovative plant the energy, and exergy simulations are fully extended and the plant comprehensively analyzed. According to mathematical simulations of the proposed plant, a MATLAB code has been extended. The results indicate that under considered initial conditions, the efficiencies of SOFC and net power generation calculated 58% and 78%, respectively and the CO₂-capture rate is obtained 79 kg/h. This study clearly shows that the integrated system reached high efficiency while having zero emissions. In addition, the efficiencies and net amount of power generation, cooling or heating output and SOFC power generation are discussed in detail as a function of different variables such utilization factor, air/fuel ratio, or SOFC inlet temperature. For enhancing the power production efficiency of SOFC, the net electricity, and CCHP exergy efficiency the plant should run in higher utilization factor and lower air/fuel ration also it's important to approximately set SOFC temperature to its ideal temperature.     

Exergy analysis of an integrated solid oxide fuel cell and organic Rankine cycle for cooling, heating and power production

The study examines a novel system that combined a solid oxide fuel cell (SOFC) and an organic Rankine cycle (ORC) for cooling, heating and power production (trigeneration) through exergy analysis. The system consists of an SOFC, an ORC, a heat exchanger and a single-effect absorption chiller. The system is modeled to produce a net electricity of around 500 kW. The study reveals that there is 3-25% gain on exergy efficiency when trigeneration is used compared with the power cycle only. Also, the study shows that as the current density of the SOFC increases, the exergy efficiencies of power cycle, cooling cogeneration, heating cogeneration and trigeneration decreases. In addition, it was shown that the effect of changing the turbine inlet pressure and ORC pump inlet temperature are insignificant on the exergy efficiencies of the power cycle, cooling cogeneration, heating cogeneration and trigeneration. Also, the study reveals that the significant sources of exergy destruction are the ORC evaporator, air heat exchanger at the SOFC inlet and heating process heat exchanger.     

Exergy based performance analysis of a solid oxide fuel cell and steam injected gas turbine hybrid power system

This paper presents exergy analysis of a hybrid solid oxide fuel cell and gas turbine (SOFC/GT) system in comparison with retrofitted system with steam injection. It is proposed to use hot gas turbine exhaust gases heat in a heat recovery steam generator to produce steam and inject it into gas turbine. Based on a steady-state model of the processes, exergy flow rates are calculated for all components and a detailed exergy analysis is performed. The components with the highest proportion of irreversibility in the hybrid systems are identified and compared. It is shown that steam injection decreases the wasted exergy from the system exhaust and boosts the exergetic efficiency by 12.11%. Also, 17.87% and 12.31% increase in exergy output and the thermal efficiency, respectively, is demonstrated. A parametric study is also performed for different values of compression pressure ratio, current density and pinch point temperature difference.