共查询到20条相似文献,搜索用时 125 毫秒
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利用相转移催化剂的协同催化作用,生产高纯度N-乙基邻甲苯胺是切实可行的。其最佳工艺条件为:邻甲苯胺:混合相转移催化剂:NaOH=1:0.1:5(摩尔比),溴乙烷为溶剂,反应温度为40℃,回流,反应时间为24h,可使N-乙基邻甲苯胺的转化率达到99.4%。 相似文献
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介绍了在N-乙基邻甲苯胺的生产过程中对邻甲苯胺含量的测定所选用的色谱分析法与化学分析法的比照实验,准确测定其含量,确保正常生产。 相似文献
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研究了由间苯二胺经单氨基酰化、氯化苄苄基化及溴乙烷乙基化合成间乙酰胺基-N-乙基-N-苄基苯胺的工艺,总收率达71.24%。 相似文献
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哌嗪-N-乙基哌嗪体系和水-N-乙基哌嗪体系汽液平衡的研究 总被引:1,自引:0,他引:1
顾飞燕 《高校化学工程学报》2000,14(3):281-284
本文实测N-乙基哌嗪的饱和蒸汽压以及用改进Rose釜测定水-N-乙基哌嗪体系在101.3kPa下汽液平衡。实测数据符合热力学一致性,并采用Wilson方程关联获得满意的结果。另外,用修正的UNIFAC模型预测哌嗪-N-乙基哌嗪与水-N-乙基哌嗪两个体系恒压(101.3kPa)汽液平衡,为化工设计提供基础数据。 相似文献
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Photoemission and conductivity measurement of poly(N‐methyl aniline) and poly(N‐ethyl aniline) films
Anjali A. Athawale Bhavana Deore Mahesh Vedpathak Sulabha K. Kulkarni 《应用聚合物科学杂志》1999,74(5):1286-1292
The studies involve the X‐ray photoelectron spectroscopy (XPS) and conductivity measurements of poly(N‐methyl aniline) and poly(N‐ethyl aniline) films deposited electrochemically at different pH values of −0.96, 2.22, and 3.78 for N‐methyl aniline and 1.10, 2.22, and 3.78 for N‐ethyl aniline. The results obtained reveal significant differences in the film properties of the two matrices as a function of pH of solution. These differences are explained on the basis of the competitive reaction products formed during polymerization in the two matrices along with the differences in the electron‐donating ability of the methyl and ethyl groups present on the nitrogen (N) atom. These results are further supported by the UV–Visible and IR data. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 74: 1286–1292, 1999 相似文献
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Jana Horniakova Kenichi Komura Hisashi Osaki Yoshihiro Kubota Yoshihiro Sugi 《Catalysis Letters》2005,102(3-4):191-196
H-form zeolites, H-FAU and H-BEA have been studied as heterogeneous catalysts for the hydroamination. They catalyzed the reaction of methyl acrylate with aniline to give N-[2-(methoxycarbonyl)ethyl]aniline (1) as a main product. H-BEA and H-FAU zeolites efficiently catalyzed the hydroamination to afford anti-Markovnikov adduct as a main product. The conversion of aniline around 55–85% was achieved within 18 h over H-BEA and H-FAU zeolites with SiO2/Al2O3 molar ratio of 25–30; however, the formation of N,N-bis[2-(methoxycarbonyl)ethyl]aniline (2) as a product of double addition of methyl acrylate to aniline has also been observed as a by-product over H-BEA and H-FAU catalysts. The influences of the reaction parameters such as temperature and catalyst amount, and type of α,β-unsaturated esters and amines have been also investigated. 相似文献
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Kinetic study of reactions of aniline and benzoyl chloride in a microstructured chemical system 下载免费PDF全文
Peijian Wang Kai Wang Jisong Zhang Guangsheng Luo 《American Institute of Chemical Engineers》2015,61(11):3804-3811
The reaction between aniline and benzoyl chloride is well known for producing high performance polymers and chemicals. But the fast main reaction and reversible consecutive side reaction make process rather complicated and no thorough kinetics study has ever been reported before. A microstructured chemical system, consisting of a micromixer, preheat exchange coiled capillaries, a delay loop, and a microhydrolyzer, was designed to carry out this reaction using N‐methyl‐2‐pyrrolidone as the solvent. A kinetic model was established, and the values of kinetic constants, pre‐exponential factors and activation energies of each reaction as well as their confidence intervals were acquired. With this model each substance concentration vs. residence time were obtained to help understand reaction process and further optimize operating conditions. Compared to earlier reports on this reaction, this microstructured chemical system provides more accurate parameters and can develop a reliable platform for kinetic study of similar chemical reactions. © 2015 American Institute of Chemical Engineers AIChE J, 61: 3804–3811, 2015 相似文献
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Jaroslav Kříž Elena N Konyushenko Miroslava Trchová Jaroslav Stejskal 《Polymer International》2011,60(9):1296-1302
The chloroform‐soluble products of aniline or (15N)aniline oxidation in alkaline medium were analysed using one‐ and two‐dimensional 1H NMR, 13C NMR and 15N NMR spectroscopy. Among the products, two were found to be prominent, namely a carbonyl‐containing semiquinonoid and a phenazine‐like structure. The probable mechanism of their formation is suggested. Copyright © 2011 Society of Chemical Industry 相似文献
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以对苯胺、丙二酸二乙酯为原料、吡啶为溶剂合成N,N'-二苯基丙二酰胺的方法进行了研究。最佳工艺条件为:原料摩尔比苯胺∶丙二酸二乙酯=2.4∶1.0,吡啶用量为苯胺质量的50%,反应时间为2h,反应温度为115℃,在DMF中进行重结晶,收率达92%以上,产品纯度为99%以上。 相似文献